{"id":1469,"date":"2022-11-11T14:03:04","date_gmt":"2022-11-11T06:03:04","guid":{"rendered":"\/\/www.30-onna.com\/?p=1469"},"modified":"2022-11-11T14:03:22","modified_gmt":"2022-11-11T06:03:22","slug":"%e5%b0%8f%e5%8a%a9%e5%89%82%e5%b8%ae%e5%8a%a9%e5%ae%9e%e7%8e%b0%e8%81%9a%e9%85%b0%e4%ba%9a%e8%83%ba%e9%9d%99%e7%94%b5%e7%ba%ba%e4%b8%9d%e6%b0%b4%e6%80%a7%e5%8c%96","status":"publish","type":"post","link":"\/\/www.30-onna.com\/archives\/1469","title":{"rendered":"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d"},"content":{"rendered":"<p>\u57fa\u4e8e\u9759\u7535\u7eba\u4e1d\u6280\u672f\u6784\u7b51\u7684\u6d77\u7ef5\u72b6\u591a\u5b54\u6750\u6599\u5177\u6709\u5b54\u9699\u7387\u9ad8\u3001\u8d28\u8f7b\u4ee5\u53ca\u591a\u529f\u80fd\u6027\u7b49\u4f18\u70b9\u3002\u968f\u7740\u8fd1\u5e74\u6765\u77ed\u7ea4\u7ef4\u6280\u672f\u53ca\u805a\u5408\u7269\u529f\u80fd\u6750\u6599\u5236\u5907\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0c\u4f7f\u5f97\u7535\u7eba\u6d77\u7ef5\u6750\u6599\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u5f00\u5b54\u4e09\u7ef4\u6750\u6599\u5f97\u5230\u5e7f\u6cdb\u7684\u5e94\u7528\u5173\u6ce8\u3002\u5176\u4e2d\uff0c\u805a\u9170\u4e9a\u80fa\uff08PI\uff09\u57fa\u7535\u7eba\u6d77\u7ef5\u591a\u5b54\u6750\u6599\u57fa\u4e8e\u5176\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\u80fd\u6210\u4e3a\u8be5\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u4f46\u662f\uff0c\u4ee5\u5f80\u7684PI\u7535\u7eba\u6280\u672f\u591a\u4ee51,4-\u4e8c\u6c27\u516d\u73af\u7b49\u975e\u6c34\u6eb6\u5242\u4e3a\u5a92\u4ecb\uff0c\u6eb6\u5242\u6bd2\u6027\u9020\u6210\u4e0d\u53ef\u907f\u514d\u7684\u73af\u5883\u6c61\u67d3\u548c\u4eba\u4f53\u5065\u5eb7\u5371\u5bb3\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u91c7\u7528\u4f20\u7edf\u6709\u673a\u6eb6\u5242\u9759\u7535\u7eba\u4e1d\u6280\u672f\u5236\u5907\u7684PI\u591a\u5b54\u7535\u7eba\u6750\u6599\u8868\u9762\u591a\u5448\u758f\u6c34\u7279\u6027\uff0c\u6781\u5927\u5730\u9650\u5236\u4e86\u5176\u5e94\u7528\u9886\u57df\u7684\u62d3\u5c55\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u5fb7\u56fd\u62dc\u7f57\u4f0a\u7279\u5927\u5b66Andreas Greiner\u548c\u97e9\u56fd\u79d1\u5b66\u6280\u672f\u5b66\u9662\uff08KAIST\uff09Il-Doo Kim\u7814\u7a76\u56e2\u961f\u5408\u4f5c\uff0c\u4ee5\u542b\u5341\u4e8c\u70f7\u57fa\u82ef\u78fa\u9178\u94a0\uff08SDBS\uff09\u8868\u9762\u6d3b\u6027\u5242\u7684\u6c34\u6eb6\u6db2\u4e3a\u6eb6\u5242\u4f53\u7cfb\uff0c\u7a81\u7834\u6027\u7684\u5b9e\u73b0\u4e86\u8868\u9762\u5177\u6709\u4eb2\u6c34\u7279\u6027PI\u7535\u7eba\u6d77\u7ef5\u591a\u5b54\u6750\u6599\uff08sPI\uff09\u7684\u5236\u5907\u3002\u57fa\u4e8eSDBS\u52a9\u5242\u6dfb\u52a0\uff0c\u6240\u5236\u5907\u591a\u5b54PI\u6750\u6599\u8868\u9762\u5448\u73b0\u53ef\u8c03\u63a7\u7684\u4eb2\u6c34\u7279\u6027\uff0c\u591a\u5b54PI\u5728\u6c34\u6eb6\u6db2\u4e2d\u5177\u6709\u4f18\u5f02\u7684\u5c3a\u5bf8\u7a33\u5b9a\u6027\uff0c\u5438\u6c34\u80fd\u529b\u8fbe5000%\u3002\u8be5\u7814\u7a76\u6210\u679c\u5728\u4eb2\u6c34\u6027\u7535\u7eba\u6d77\u7ef5\u6750\u6599\u5236\u5907\u65b9\u9762\u5177\u6709\u91cc\u7a0b\u7891\u610f\u4e49\uff0c\u5728\u751f\u7269\u7ec4\u7ec7\u5de5\u7a0b\u3001\u6cb9\u6c34\u5206\u79bb\u7b49\u9886\u57df\u5177\u6709\u5e7f\u9614\u7684\u6280\u672f\u5e94\u7528\u524d\u666f\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-1470\" src=\"\/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146342184.jpg\" width=\"880\" height=\"911\" srcset=\"\/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146342184.jpg 880w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146342184-338x350.jpg 338w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146342184-768x795.jpg 768w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146342184-220x228.jpg 220w\" sizes=\"(max-width: 880px) 100vw, 880px\" title=\"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d\u63d2\u56fe\" alt=\"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d\u63d2\u56fe\" \/><\/p>\n<p>PI\u7535\u7eba\u6d77\u7ef5\u5236\u5907\u8fc7\u7a0b\u53ca\u8868\u9762\u6027\u80fd\u5c55\u793a\u3002\u56fe\u7247\u6765\u6e90\uff1aACS Appl. Mater. Interfaces<\/p>\n<p>\u901a\u8fc7\u9ad8\u526a\u5207\u6df7\u5408\u5c06\u957fPI\u7ea4\u7ef4\u88c1\u526a\u6210\u77ed\u7ea4\u7ef4\uff0c\u6dfb\u52a0\u5c11\u91cf\uff08e.g., 1 wt %\uff09SDBS\u8868\u9762\u6d3b\u6027\u5242\u4e3a\u5206\u6563\u52a9\u5242\u540e\uff0c\u5176\u80fd\u591f\u5728\u6c34\u6eb6\u6db2\u4e2d\u5b9e\u73b0\u7a33\u5b9a\u5206\u6563\u3002\u8fdb\u4e00\u6b65\u52a0\u5165\u805a\u9170\u80fa\u9178\u6eb6\u6db2\u540e\uff0c\u6df7\u5408\u6eb6\u6db2\u4e5f\u5448\u73b0\u8f83\u597d\u7684\u76f8\u5bb9\u6027\uff1b\u5176\u4e2d\u805a\u9170\u80fa\u9178\u5728\u6b64\u540e\u7535\u7eba\u5236\u5907sPI\u6d77\u7ef5\u6750\u6599\u8fc7\u7a0b\u4e2d\u8d77\u5230\u7c98\u7ed3\u5242\u7684\u4f5c\u7528\u3001\u5f15\u5165SDBS\u8868\u9762\u6d3b\u6027\u5242\u540esPI\u4e9a\u80fa\u5316\u56fa\u5316\u6e29\u5ea6\u63d0\u9ad8\u81f3280 \u2103\uff0c\u8fd9\u4e24\u4e2a\u65b9\u9762\u56e0\u7d20\u662f\u4fdd\u8bc1PI\u6d77\u7ef5\u6750\u6599\u4f18\u5f02\u673a\u68b0\u6027\u80fd\u7684\u5173\u952e\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-1471\" src=\"\/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146370123.jpg\" width=\"880\" height=\"304\" srcset=\"\/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146370123.jpg 880w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146370123-350x121.jpg 350w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146370123-768x265.jpg 768w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146370123-220x76.jpg 220w\" sizes=\"(max-width: 880px) 100vw, 880px\" title=\"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d\u63d2\u56fe1\" alt=\"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d\u63d2\u56fe1\" \/><\/p>\n<p>sPI\u6d77\u7ef5\u6750\u6599\u8868\u9762\u4eb2\u758f\u6027\u53ca\u5438\u6536\u6027\u80fd\u8c03\u63a7\u3002\u56fe\u7247\u6765\u6e90\uff1aACS Appl. Mater. Interfaces<\/p>\n<p>\u533a\u522b\u4e8e\u4f20\u7edf\u7684\u9759\u7535\u7eba\u4e1d\u6280\u672f\uff0c\u52a0\u5165SDBS\u4e3a\u52a9\u5242\u540e\u6240\u5236\u5907sPI\u6d77\u7ef5\u6750\u6599\u8868\u9762\u5448\u73b0\u660e\u663e\u7684\u4eb2\u6c34\u7279\u6027\uff08\u6c34\u6ef4\u5b8c\u5168\u6da6\u6e7f\u6240\u9700\u65f6\u95f4\uff1c100 ms\uff09\u3002\u540c\u65f6\uff0c\u7cfb\u7edf\u7814\u7a76\u8868\u660e\u901a\u8fc7\u8c03\u63a7SDBS\u8868\u9762\u6d3b\u6027\u5242\u6dfb\u52a0\u6d53\u5ea6\u4ee5\u53ca\u6eb6\u6db2\u4e2dPI\u77ed\u7ea4\u7ef4\u542b\u91cf\u80fd\u591f\u5bf9sPI\u6d77\u7ef5\u6750\u6599\u4eb2\u6c34\u6027\uff08\u6c34\u63a5\u89e6\u89d2\uff09\u548c\u5438\u6c34\u80fd\u529b\u8fdb\u884c\u8c03\u63a7\u3002\u5176\u4e2d\uff0c\u7814\u7a76\u8868\u660e2.0 wt%\u542b\u91cfSDBS\u7684\u52a0\u5165\u8db3\u4ee5\u4fdd\u8bc1\u6240\u5236\u5907PI\u6750\u6599\u8868\u9762\u5448\u73b0\u4eb2\u6c34\u6027\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-1472\" src=\"\/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146543552.jpg\" width=\"600\" height=\"402\" srcset=\"\/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146543552.jpg 600w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146543552-350x235.jpg 350w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146543552-220x147.jpg 220w\" sizes=\"(max-width: 600px) 100vw, 600px\" title=\"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d\u63d2\u56fe2\" alt=\"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d\u63d2\u56fe2\" \/><\/p>\n<p>sPI\u6d77\u7ef5\u6750\u6599\u673a\u68b0\u6027\u80fd\u6d4b\u8bd5\u3002\u56fe\u7247\u6765\u6e90\uff1aACS Appl. Mater. Interfaces<\/p>\n<p>\u540c\u65f6\uff0c\u867d\u7136\u4f20\u7edfPI\u6750\u8d28\u5177\u6709\u56fa\u6709\u7684\u758f\u6c34\u6027\uff0c\u8be5\u7814\u7a76\u4e2d\u6240\u5236\u5907sPI\u6d77\u7ef5\u6750\u6599\u5448\u73b0\u5353\u8d8a\u7684\u5438\u6c34\u80fd\u529b\u4ee5\u53ca\u5faa\u73af\u6d4b\u8bd5\u6027\u80fd\u7a33\u5b9a\u6027\uff1b\u5f53SDBS\u542b\u91cf\u4e3aPI\u7ea4\u7ef4\u8d28\u91cf10 wt%\u65f6\uff0csPI\u6d77\u7ef5\u6750\u6599\uff08SDBS(10%)-sPI\uff09\u521d\u59cb\u5438\u6c34\u7387\u8fbe\u52305000 wt %\uff08\u4f73\uff09\u3002\u6b64\u5916\uff0c\u5faa\u73af\u538b\u7f29\u6027\u80fd\u6d4b\u8bd5\u8868\u660esPI\u6d77\u7ef5\u6750\u6599\u4f53\u7cfb\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u548c\u591a\u5b54\u5c3a\u5bf8\u7a33\u5b9a\u6027\u3002\u00a0\u805a\u4e19\u70ef\u8148\u591a\u5b54\u6d77\u7ef5\u7684\u5236\u5907\u5e94\u7528\u62d3\u5c55\u3002\u56fe\u7247\u6765\u6e90\uff1aACS Appl. Mater. Interfaces<\/p>\n<p>\u4e3a\u5c55\u793a\u8be5\u9759\u7535\u7eba\u4e1d\u6280\u672f\u7684\u666e\u9002\u6027\uff0c\u7814\u7a76\u4eba\u5458\u8fdb\u4e00\u6b65\u91c7\u7528SDBS\u8f85\u52a9\u5236\u5907\u4e86\u805a\u4e19\u70ef\u8148\uff08PAN\uff09\u6d77\u7ef5\u6750\u6599\u3002\u6dfb\u52a010 wt % SDBS\uff0c\u6240\u5236\u5907PAN\u591a\u5b54\u6750\u6599\u5bc6\u5ea6\u4e3a5.7 mg cm-3\u3001\u6750\u6599\u8868\u9762\u5448\u5f3a\u4eb2\u6c34\u6027\u4e14\u5177\u6709\u5353\u8d8a\u7684\u538b\u7f29\u5faa\u73af\u6d4b\u8bd5\uff08100\u4f59\u6b21\uff09\u6027\u80fd\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u57fa\u4e8esPI\u6d77\u7ef5\u6750\u6599\u8868\u9762\u7684\u4eb2\u6c34\u7279\u6027\uff0c\u591a\u5b54\u6750\u6599\u53ef\u4f5c\u4e3a\u83cc\u819c\u57fa\u5e95\u7528\u4e8e\u4e0d\u540c\u529f\u80fd\u751f\u7269\u819c\u7684\u57f9\u80b2\uff0c\u5728\u751f\u7269\u71c3\u6599\u7535\u6c60\u7b49\u9886\u57df\u7684\u5177\u6709\u91cd\u8981\u7684\u6f5c\u5728\u5e94\u7528\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-1473\" src=\"\/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146523988.jpg\" width=\"500\" height=\"750\" srcset=\"\/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146523988.jpg 500w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146523988-233x350.jpg 233w, \/\/www.30-onna.com\/wp-content\/uploads\/2022\/11\/1668146523988-220x330.jpg 220w\" sizes=\"(max-width: 500px) 100vw, 500px\" title=\"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d\u63d2\u56fe3\" alt=\"\u5c0f\u52a9\u5242\u5e2e\u52a9\u5b9e\u73b0\u805a\u9170\u4e9a\u80fa\u9759\u7535\u7eba\u4e1d\u201c\u6c34\u6027\u5316\u201d\u63d2\u56fe3\" \/><\/p>\n<p>sPI\u6d77\u7ef5\u6750\u6599\u7ec6\u83cc\u57f9\u517b\u5e94\u7528\u3002\u56fe\u7247\u6765\u6e90\uff1aACS Appl. Mater. Interfaces<\/p>\n<p>\u603b\u7ed3<\/p>\n<p>\u8868\u9762\u6d3b\u6027\u5242\u4f5c\u4e3a\u4e00\u79cd\u5178\u578b\u7684\u4e24\u4eb2\u6027\u5927\u5206\u5b50\u5316\u5408\u7269\uff0c\u5e7f\u6cdb\u7684\u5e94\u7528\u4e8e\u5de5\u4e1a\u751f\u4ea7\u548c\u65e5\u5e38\u751f\u6d3b\u4e2d\u3002\u8be5\u7814\u7a76\u521b\u9020\u6027\u7684\u4ee5\u5fae\u91cf\u4f20\u7edfSDBS\u4e3a\u6eb6\u6db2\u52a9\u5242\uff0c\u5b9e\u73b0\u4e86\u805a\u9170\u4e9a\u80fa\u7b49\u805a\u5408\u7269\u6750\u6599\u4f53\u7cfb\u9759\u7535\u7eba\u4e1d\u6280\u201c\u6c34\u6027\u5316\u201d\u7b80\u4fbf\u5236\u5907\u3002\u8be5\u7814\u7a76\u6210\u679c\u4e2d\u591a\u5b54\u6750\u6599\u8868\u9762\u4eb2\u6c34\u6539\u6027\u6280\u672f\u53ca\u5176\u7b56\u7565\u7684\u666e\u9002\u6027\uff0c\u5c06\u6781\u5927\u5730\u7a81\u7834\u4f20\u7edf\u805a\u5408\u7269\u6750\u6599\u56fa\u6709\u758f\u6c34\u7279\u6027\u5e26\u6765\u7684\u5e94\u7528\u5c40\u9650\u6027\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u57fa\u4e8e\u9759\u7535\u7eba\u4e1d\u6280\u672f\u6784\u7b51\u7684\u6d77\u7ef5\u72b6\u591a\u5b54\u6750\u6599\u5177\u6709\u5b54\u9699\u7387\u9ad8\u3001\u8d28\u8f7b\u4ee5\u53ca\u591a\u529f\u80fd\u6027\u7b49\u4f18\u70b9\u3002\u968f\u7740\u8fd1\u5e74\u6765\u77ed\u7ea4\u7ef4\u6280\u672f\u53ca\u805a\u5408\u7269\u529f\u80fd\u6750\u6599\u5236\u5907\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0c\u4f7f\u5f97\u7535\u7eba\u6d77\u7ef5\u6750\u6599\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u5f00\u5b54\u4e09\u7ef4\u6750\u6599\u5f97\u5230\u5e7f\u6cdb\u7684\u5e94\u7528\u5173\u6ce8\u3002\u5176\u4e2d\uff0c\u805a\u9170&#8230; <\/p>\n","protected":false},"author":2,"featured_media":1470,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"_links":{"self":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/1469"}],"collection":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/comments?post=1469"}],"version-history":[{"count":1,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/1469\/revisions"}],"predecessor-version":[{"id":1474,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/1469\/revisions\/1474"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/media\/1470"}],"wp:attachment":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/media?parent=1469"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/categories?post=1469"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/tags?post=1469"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}