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<\/p>\n
1. Adv.Mater\uff1a\u7535\u50ac\u5316\u5c3f\u7d20\u5408\u6210\u8fc7\u7a0b\u4e2d\u94dc\u5355\u539f\u5b50\u4e0e\u56e2\u7c07\u4e4b\u95f4\u7684\u52a8\u6001\u91cd\u6784<\/p>\n
\u50ac\u5316\u5242\u7684\u5408\u6210\uff0c\u8fd9\u79cd\u50ac\u5316\u5242\u5728\u5e94\u7528\u7535\u52bf\u4e3a-1.6 V versus RHE\u6761\u4ef6\u4e0b\u7684\u5e73\u5747\u5c3f\u7d20\u4ea7\u7387\u4e3a52.84 mmol h-1 gcat-1\u3002XAS\u5149\u8c31\u663e\u793a\u4e86\u5728\u7535\u89e3\u8fc7\u7a0b\u4e2d\u94dc\u5355\u539f\u5b50\uff08Cu1\uff09\u5230\u56e2\u7c07\uff08Cu4\uff09\u7684\u91cd\u6784\uff0c\u8fd9\u79cd\u7535\u5316\u5b66\u91cd\u6784\u7684Cu4\u56e2\u7c07\u624d\u662f\u7535\u50ac\u5316\u5c3f\u7d20\u7684\u771f\u6b63\u6d3b\u6027\u4f4d\u70b9\u3002\u4f7f\u7528SR-FTIR\u548cDFT\u8ba1\u7b97\u9a8c\u8bc1\u4e86 Cu4\u4e0a\u6709\u5229\u7684\u78b3\u6c2e\u5076\u8054\u53cd\u5e94\u548c\u5c3f\u7d20\u5f62\u6210\u3002\u5f53\u65bd\u52a0\u7684\u7535\u52bf\u5207\u6362\u4e3a\u5f00\u8def\u7535\u52bf\u65f6\uff0c\u56e2\u7c07\u4f1a\u52a8\u6001\u548c\u53ef\u9006\u5730\u8f6c\u53d8\u4e3a\u5355\u539f\u5b50\u6784\u578b\uff0c\u4ece\u800c\u8d4b\u4e88\u50ac\u5316\u5242\u4f18\u5f02\u7684\u7ed3\u6784\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cDynamic Reconstitution Between Copper Single atoms and Clusters for Electrocatalytic Urea synthesis\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Materials\u4e0a<\/p>\n
<\/p>\n
\u6e05\u534e\u5927\u5b66\u6c34\u8d28\u4e0e\u6c34\u751f\u6001\u7814\u7a76\u4e2d\u5fc3\u66f2\u4e45\u8f89\u9662\u58eb\u56e2\u961f\u5b89\u6653\u5f3a\u526f\u7814\u7a76\u5458\u4e0e\u5316\u5de5\u7cfb\u5510\u519b\u65fa\u6559\u6388\u3001\u5317\u822a\u5218\u5229\u6c11\u6559\u6388\u5f00\u5c55\u5408\u4f5c\uff0c\u63d0\u51fa\u4e00\u79cd\u94a0\u8f85\u52a9\u7684\u5149\u8bf1\u5bfc\u7ec4\u88c5 (SPA) \u65b0\u7b56\u7565\u3002\u901a\u8fc7\u8f7d\u4f53\u8868\u9762\u94a0\u79bb\u5b50\u4e0e\u91d1\u539f\u5b50\u7279\u6b8a\u7684\u76f8\u4e92\u4f5c\u7528\u5f62\u6210\u6e38\u79bb\u4e8e\u6c27\u5316\u949b\u8868\u9762\u7684\u7a33\u5b9a\u539f\u5b50\u5bf9\uff0c\u540c\u65f6\u501f\u52a9\u5149\u573a\u4f5c\u7528\u9a71\u52a8\u6bd7\u90bb\u91d1\u539f\u5b50\u8fc1\u79fb\u805a\u96c6\u6210\u7c07\uff0c\u6240\u751f\u4ea7\u7684\u53cc\u4f4d\u70b9\u534f\u540c\u50ac\u5316\u5242\u5728\u5149\u89e3\u6c34\u5236\u6c22\u53cd\u5e94\u4e2d\u5448\u73b0\u51fa\u4e24\u4e2a\u6570\u91cf\u7ea7\u63d0\u5347\u7684\u50ac\u5316\u6548\u7387\uff0c\u4e3a\u539f\u5b50\u5c3a\u5ea6\u4e0a\u201c\u81ea\u4e0b\u800c\u4e0a\u201d\u6784\u7b51\u5355\u539f\u5b50\/\u7eb3\u7c73\u7c07\u534f\u540c\u7684\u591a\u70b9\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cSodium-Directed Photon-Induced Assembly Strategy for Preparing Multisite Catalysts with High Atomic Utilization Efficiency\u201d\u53d1\u8868\u5728Journal of the American Chemical Society\u4e0a\u3002<\/p>\n
\u4f26\u6566\u5e1d\u56fd\u7406\u5de5\u5b66\u9662\u7687\u5bb6\u77ff\u4e1a\u5b66\u9662\u6750\u6599\u7cfbIfan E. L. Stephens\u6559\u6388\u56e2\u961f\u4e0e\u5316\u5b66\u5de5\u7a0b\u7cfbMaria-Magdalena Titirici\u6559\u6388\u56e2\u961f\u8054\u5408\u63cf\u8ff0\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u65b9\u6cd5\uff0c\u901a\u8fc7\u4f7f\u7528Mg2+\u76d0\u4f5c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u6a21\u677f\u548c\u5b54\u9699\u5242\uff0c\u4ee5\u53ca\u53e6\u4e00\u79cd\u6709\u673a\u524d\u9a71\u4f532,4,6-\u4e09\u6c28\u57fa\u5627\u5576\uff08TAP\uff09\u5236\u5907\u4e86\u591a\u5b54\u7684N\u63ba\u6742\u78b3\u5bbf\u4e3b\uff0c\u7136\u540e\u5c06\u5176\u7528\u4e8eFe\u914d\u4f4d\uff0c\u4ece\u800c\u5236\u5907\u4e86\u5177\u6709\u521b\u7eaa\u5f55\u9ad8FeNx\u7535\u5316\u5b66\u5229\u7528\u7387\u7684FeNC\u6750\u6599\u3002\u4e0eFe\u4e0d\u540c\uff08Fe\u5728\u70ed\u89e3\u65f6\u5f62\u6210\u6c2e\u5316\u7269\u548c\u78b3\u5316\u7269\uff09\uff0cMg2+\u662f\u4e00\u79cd\u8def\u6613\u65af\u9178\u6027\u91d1\u5c5e\u9633\u79bb\u5b50\uff0c\u5b83\u53ef\u4ee5\u5f62\u6210Nx\u57fa\u56e2\u5e76\u4ea7\u751f\u5b54\u9699\u3002TAP\u4e0e\u6c34\u5408Mg2+\u76d0\u7684\u6c34\u5206\u5b50\u6709\u6548\u5730\u76f8\u4e92\u4f5c\u7528\uff0c\u5e76\u5728\u70ed\u89e3\u65f6\u7194\u5316\uff0c\u4ece\u800c\u5b9e\u73b0\u6709\u6548\u7684\u805a\u5408\u548cMg\u5728\u6574\u4e2a\u6750\u6599\u4e2d\u7684\u5747\u5300\u5206\u5e03\u3002Fe\u968f\u540e\u5728\u9ad8\u6bd4\u8868\u9762\u79ef\u6c2e\u63ba\u6742\u78b3\uff08~3295 m2 g-1\uff09\u4e2d\u901a\u8fc7\u4f4e\u6e29\u6e7f\u6cd5\u6d78\u6e0d\u4ea7\u751f\u9ad8\u53ef\u7528\u7684FeNx\u6d3b\u6027\u4f4d\u70b9\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u70ed\u91cd\u5206\u6790\u3001\u8d28\u8c31\u3001\u56fa\u6001\u6838\u78c1\u5171\u632f\u548cX\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u7b49\u65b9\u6cd5\uff0c\u5bf9\u6240\u5236\u5907\u6750\u6599\u7684\u805a\u5408\u9014\u5f84\u548c\u751f\u957f\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\u3002<\/p>\n
\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u626b\u63cf\u900f\u5c04\u7535\u955c\u548c\u80fd\u91cf\u8272\u6563X\u5c04\u7ebf\u8bc1\u5b9e\u4e86Fe\u7684\u539f\u5b50\u8272\u6563\uff0c\u800c\u901a\u8fc7X\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u3001\u7535\u5b50\u987a\u78c1\u5171\u632f\u548c\u4f4e\u6e29\u7a46\u65af\u5821\u5c14\u5149\u8c31\u9610\u660e\u4e86\u6d3b\u6027\u4f4d\u70b9\u7684\u7ed3\u6784\uff0c\u5176\u4e2d\u4e3b\u8981\u7684FeNx\u4f4d\u70b9\u7531\u8f74\u5411\u914d\u4f53\u4e94\u914d\u4f4d\u5f62\u6210\u3002\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u7528\u65cb\u8f6c\u5706\u76d8\u7535\u6781\u6d4b\u91cf\u8bc4\u4f30\u4e86\u50ac\u5316\u5242\u5bf9O2\u8fd8\u539f\u7684\u6027\u80fd\uff0c\u53d1\u73b0\u53ef\u4ee5\u4ece\u539f\u4f4d\u4e9a\u785d\u9178\u76d0\u5265\u79bb\u4e2d\u4f7f\u50ac\u5316\u4f53\u7cfb\u83b7\u5f97\u9ad8\u4f4d\u7f6e\u5bc6\u5ea6\uff0c\u4f4e\u8f6c\u6362\u9891\u7387\u548c\u9ad8\u5229\u7528\u7387\u3002\u540e\uff0c\u4f7f\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u6765\u8bc4\u4f30\u8f74\u5411\u914d\u4f53\u5bf9\u6a21\u578bFeN4\u5421\u5576\u548c\u5421\u54af\u4f4d\u70b9O2\u8fd8\u539f\u6d3b\u6027\u7684\u5f71\u54cd\uff0c\u4e0e\u666e\u901aFeN4\u4f4d\u70b9\u76f8\u6bd4\uff0c\u7814\u7a76\u4eba\u5458\u89c2\u5bdf\u5230\u4e0d\u540c\u8f74\u5411\u914d\u4f53\u7684OH\u7ed3\u5408\u80fd\u548c\u6d3b\u6027\u53d1\u751f\u4e86\u5f88\u5927\u53d8\u5316\u3002<\/p>\n
\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cFeNC Oxygen Reduction Electrocatalyst with High Utilisation Penta-coordinated sites\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aAdvanced Materials\u4e0a\u3002<\/p>\n
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\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u9648\u4f1f\u6559\u6388\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u5149\u7535\u5316\u5b66\u65b9\u6cd5\uff0c\u901a\u8fc7\u4f7f\u7528\u951a\u5b9a\u5728\u6709\u7f3a\u9677\u7684TiO2\u7eb3\u7c73\u68d2\u9635\u5217\u4e0a\u7684\u5355\u539f\u5b50Pt\u4f5c\u4e3a\u5149\u7535\u9633\u6781\uff0c\u9009\u62e9\u6027\u5730\u5c06\u8461\u8404\u7cd6\u6c27\u5316\u6210\u9ad8\u9644\u52a0\u503c\u7684\u8461\u7cd6\u4e8c\u9178\u3002\u7531\u6c27\u7a7a\u4f4d\u5f15\u8d77\u7684\u7f3a\u9677\u7ed3\u6784\u53ef\u4ee5\u540c\u65f6\u8c03\u8282\u7535\u8377\u8f7d\u6d41\u5b50\u7684\u52a8\u529b\u5b66\u548c\u80fd\u5e26\u7ed3\u6784\u3002\u901a\u8fc7\u4f18\u5316\u6c27\u7a7a\u4f4d\uff0c\u6709\u7f3a\u9677\u7684TiO2\u5149\u7535\u9633\u6781\u663e\u793a\u51fa\u6781\u5927\u7684\u7535\u8377\u5206\u79bb\u80fd\u529b\u548c\u660e\u663e\u589e\u5f3a\u7684C6\u4ea7\u54c1\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u5e26\u6709\u5355\u539f\u5b50Pt\u7684\u7f3a\u9677TiO2\u57280.6V\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e861.91 mA cm-2\u7684\u8461\u8404\u7cd6\u6c27\u5316\u5149\u7535\u6d41\u5bc6\u5ea6\uff0c\u4ece\u800c\u5728\u6a21\u62df\u9633\u5149\u7167\u5c04\u4e0b\u8461\u7cd6\u4e8c\u9178\u4ea7\u7387\u4e3a84.3%\u3002\u8be5\u8bba\u6587\u4ee5\u9898\u4e3a\u201cSelective photoelectrochemical oxidation of glucose to glucaric acid by single atom Pt decorated defective TiO2\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aNature Communications\u4e0a\uff0cTian Zhuangliu\u4e3a\u672c\u6587\u7684\u4e00\u4f5c\u517c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n
\u82f1\u56fd\u4f26\u6566\u5927\u5b66\u5b66\u9662\u5510\u519b\u65fa\u6559\u6388\u4e0e\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240\u738b\u7231\u7434\u7814\u7a76\u5458\u8054\u5408\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u7531\u9650\u5236\u5728\u4e8c\u6c27\u5316\u949b\u8868\u9762\u7684\u954d\u5355\u539f\u5b50\u7ec4\u6210\u9ad8\u9009\u62e9\u6027\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u5c06\u7518\u6cb9\u8f6c\u5316\u4e3a\u9ad8\u4ef7\u503c\u4ea7\u54c1\u7f9f\u4e59\u919b\u3002\u5728\u5149\u7684\u9a71\u52a8\u4e0b\uff0c\u50ac\u5316\u5242\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u5229\u7528\u7a7a\u6c14\u4f5c\u4e3a\u7eff\u8272\u6c27\u5316\u5242\u8fdb\u884c\u53cd\u5e94\u3002\u4f18\u5316\u540e\u7684\u50ac\u5316\u5242\u5bf9\u7f9f\u4e59\u919b\u7684\u9009\u62e9\u6027\u8d85\u8fc760%\uff0c\u4ea7\u73871058 \u03bcmol\u00b7gCat-1\u00b7h-1\uff0c\u8f6c\u6362\u6570\u6bd4NiOx\u7eb3\u7c73\u7c92\u5b50\u4fee\u9970\u7684TiO2\u5149\u50ac\u5316\u5242\u9ad8\u8fd13\u500d\u3002\u4e0d\u540c\u7684\u7406\u5316\u6027\u8d28\u8868\u5f81\u63ed\u793a\u4e86\u5355\u539f\u5b50\u954d\u7684\u72ec\u7279\u529f\u80fd\uff0c\u5b83\u53ef\u4ee5\u663e\u8457\u4fc3\u8fdb\u6c27\u5438\u9644\u3001\u5145\u5f53\u7535\u5b50\u9631\u5e76\u52a0\u901f\u8d85\u6c27\u5316\u7269\u81ea\u7531\u57fa\u7684\u4ea7\u751f\uff0c\u4ece\u800c\u63d0\u9ad8\u5bf9\u7f9f\u4e59\u919b\u7684\u9009\u62e9\u6027\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cHighly selective transformation of biomass derivatives to valuable chemicals by single-atom photocatalyst Ni\/TiO2\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aAdv. Mater.\u4e0a\u3002<\/p>\n
6. \u89e3\u6790\u5916\u56f4N\u5bf9Ru\u5355\u539f\u5b50\u50ac\u5316\u4e2d\u5fc3\u5f71\u54cd\uff0c\u5b9e\u73b0\u9ad8\u6548\u4e19\u70f7\u8131\u6c22<\/p>\n
\u5f00\u53d1\u4e86\u4e00\u79cd\u57fa\u4e8e\u6c2e\u63ba\u6742\u78b3\u4e0a\u7684Ru\u5355\u539f\u5b50(Ru1\/NC)\u9ad8\u7a33\u5b9a\u4e19\u70f7\u8131\u6c22\u50ac\u5316\u5242\u3002Ru1\/NC\u7684\u8f6c\u6362\u9891\u7387\u6bd4Ru\u7eb3\u7c73\u9897\u7c92\u7684\u7ffb\u8f6c\u9891\u7387\u81f3\u5c11\u9ad83\u500d\u3002\u5b9e\u9a8c\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7814\u7a76\u63ed\u793a\u4e86Ru1\u4e2d\u5fc3\u5468\u56f4\u6c2e\u7684\u91cd\u8981\u4f5c\u7528\u3002\u5185\u5c42N\u7a33\u5b9a\u4e86\u539f\u5b50\u5206\u6563\u7684Ru\uff0c\u6291\u5236\u4e86\u4e19\u70f7\u88c2\u89e3\uff0c\u800c\u5916\u5c42N\u4fc3\u8fdb\u4e86Ru1\u4e2d\u5fc3\u7684\u7535\u5b50\u79ef\u7d2f\uff0c\u4f7fRu1\u4e0e\u4e19\u70ef\u4e4b\u95f4\u4ea7\u751f\u660e\u663e\u7684\u7535\u8377\u6392\u65a5\uff0c\u4fc3\u8fdb\u4e86\u5176\u89e3\u5438\u3002\u5728\u5355\u539f\u5b50Ru\u4f4d\u70b9\u4e0a\uff0c\u5185\u5c42\u548c\u5916\u5c42N\u7684\u7ec4\u5408\u4f5c\u7528\u6709\u52a9\u4e8eRu1\/NC\u7684\u9ad8\u6548\u7387\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cPeripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation\u201d\u53d1\u8868\u5728\u56fd\u9645\u671f\u520aNature Catalysis\u4e0a<\/p>\n
7. Nature\u5b50\u520a\uff1a\u6c22\u53d6\u4ee3\u7684\u77f3\u58a8\u7094\u8f85\u52a9\u7684\u8d85\u5feb\u706b\u82b1\u5408\u6210\u4e9a\u7a33\u6001\u7eb3\u7c73\u6750\u6599<\/p>\n
\u65af\u5766\u798f\u5927\u5b66\u5d14\u5c79\u6559\u6388\u5229\u7528\u53d6\u4ee3\u6c22\u7684\u77f3\u58a8\u7094\u6c14\u51dd\u80f6(HGDY)\u5f00\u53d1\u4e86\u8d85\u5feb\u9ad8\u6e29\u5e73\u53f0\u3002HGDY\u662f\u4e8c\u7ef4sp\/sp2\u5171\u6742\u5316\u78b3\u7f51\u7edc\uff0c\u4e3a\u4e9a\u7a33\u6001\u7eb3\u7c73\u6750\u6599\u63d0\u4f9b\u4e86\u9ad8\u5bc6\u5ea6\u4f4d\u70b9\u3002\u4f5c\u8005\u8bbe\u8ba1\u4e86\u6c22\u53d6\u4ee3\u77f3\u58a8\u7094\u8f85\u52a9\u7684\u8d85\u5feb\u706b\u82b1\u5408\u6210(GAUSS)\u5b9e\u73b0\u4e8640ms\u5185\u6e29\u5ea6\u8fbe\u52301640 K\u3002\u901a\u8fc7\u5c06\u94dd\u7eb3\u7c73\u9897\u7c92\u548c\u6c27\u5316\u5242\u7ed3\u5408\u8d77\u6765\uff0cGAUSS\u4ec5\u57288 ms\u5185\u5c31\u8fbe\u5230\u4e863286 K\u7684\u663e\u8457\u6e29\u5ea6\uff0c\u52a0\u70ed\u901f\u7387\u5927\u4e8e105K s-1\u3002\u5229\u7528GAUSS\u5e73\u53f0\u6210\u529f\u5408\u6210\u4e86\u4e00\u4e2a\u5305\u62ec\u5355\u539f\u5b50\u3001\u9ad8\u71b5\u5408\u91d1\u548c\u9ad8\u71b5\u6c27\u5316\u7269\u7684\u4e9a\u7a33\u6001\u7eb3\u7c73\u6750\u6599\u5e93\u3002\u7535\u5316\u5b66\u6d4b\u91cf\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8868\u660e\uff0c\u7528GAUSS\u5e73\u53f0\u5408\u6210\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u4fc3\u8fdb\u4e86\u5168\u56fa\u6001\u9502-\u786b\u7535\u6c60\u7684\u9502-\u786b\u8f6c\u6362\u52a8\u529b\u5b66\u3002\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201cHydrogen-substituted graphdiyne-assisted ultrafast sparking synthesis of metastable nanomaterials\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aNature Nanotechnology\u4e0a\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"
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