{"id":3560,"date":"2024-04-07T13:40:39","date_gmt":"2024-04-07T05:40:39","guid":{"rendered":"\/\/www.30-onna.com\/?p=3560"},"modified":"2024-04-07T13:53:49","modified_gmt":"2024-04-07T05:53:49","slug":"3560","status":"publish","type":"post","link":"\/\/www.30-onna.com\/archives\/3560","title":{"rendered":"\u5206\u5b50\u7b5b\u7684\u6982\u5ff5"},"content":{"rendered":"

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Mx\/n[(AlO2)x(SiO2)y] ZH2O<\/p>\n

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A\u578b\u5206\u5b50\u7b5b<\/p>\n

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X-\u578b\u548cY-\u578b\u5206\u5b50\u7b5b<\/p>\n

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\u9ad8\u7845\u6cb8\u77f3ZSM\uff08Zeolite Socony Mobil\uff09\u578b\u5206\u5b50\u7b5b<\/p>\n

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\u78f7\u9178\u94dd\u7cfb\u5206\u5b50\u7b5b<\/p>\n

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4\u3001\u5206\u5b50\u7b5b\u50ac\u5316\u5242\u7684\u50ac\u5316\u4f5c\u7528\u673a\u7406<\/p>\n

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\"\u5206\u5b50\u7b5b\u7684\u6982\u5ff5\u63d2\u56fe1\"<\/p>\n

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\uff082\uff09\u62e9\u5f62\u9009\u62e9\u6027\u7684\u8c03\u53d8<\/p>\n

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1.\u91d1\u5c5e\u50ac\u5316\u5242\u6982\u8ff0<\/p>\n

\u91d1\u5c5e\u50ac\u5316\u5242\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u5de5\u4e1a\u50ac\u5316\u5242\u3002\u4e3b\u8981\u5305\u62ec\u5757\u72b6\u50ac\u5316\u5242\uff0c\u5982\u7535\u89e3\u94f6\u50ac\u5316\u5242\u3001\u878d\u94c1\u50ac\u5316\u5242\u3001\u94c2\u7f51\u50ac\u5316\u5242\u7b49\uff1b\u5206\u6563\u6216\u8005\u8d1f\u8f7d\u578b\u7684\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5982Pt-Re\/-Al2O3\u91cd\u6574\u50ac\u5316\u5242\uff0cNi\/Al2O3\u52a0\u6c22\u50ac\u5316\u5242\u7b49\uff1b<\/p>\n

6.3 \u91d1\u5c5e\u50ac\u5316\u5242\u53ca\u5176\u50ac\u5316\u5242\u4f5c\u7528\u673a\u7406<\/p>\n

\u91d1\u5c5e\u4e92\u5316\u7269\u50ac\u5316\u5242\uff0c\u5982LaNi5\u53ef\u50ac\u5316\u5408\u6210\u6c14\u8f6c\u5316\u4e3a\u70c3\uff0c\u662f70\u5e74\u4ee3\u5f00\u53d1\u7684\u4e00\u7c7b\u65b0\u578b\u50ac\u5316\u5242\uff0c\u4e5f\u662f\u78c1\u6027\u6750\u6599\u3001\u50a8\u6c22\u6750\u6599\uff1b\u91d1\u5c5e\u7c07\u72b6\u7269\u50ac\u5316\u5242\uff0c\u5982\u70ef\u70c3\u6c22\u919b\u5316\u5236\u7fb0\u57fa\u5316\u5408\u7269\u7684\u591a\u6838Fe3(CO)12\u50ac\u5316\u5242\uff0c\u81f3\u5c11\u8981\u6709\u4e24\u4e2a\u4ee5\u4e0a\u7684\u91d1\u5c5e\u539f\u5b50\uff0c\u4ee5\u6ee1\u8db3\u50ac\u5316\u5242\u6d3b\u5316\u5f15\u53d1\u6240\u5fc5\u9700\u3002\u8fd95\u7c7b\u91d1\u5c5e\u50ac\u5316\u5242\u4e2d\uff0c\u524d\u4e24\u7c7b\u662f\u4e3b\u8981\u7684\uff0c\u540e\u4e09\u7c7b\u572820\u4e16\u7eaa70\u5e74\u4ee3\u4ee5\u6765\u6709\u65b0\u7684\u53d1\u5c55\u3002<\/p>\n

\u51e0\u4e4e\u6240\u6709\u7684\u91d1\u5c5e\u50ac\u5316\u5242\u90fd\u662f\u8fc7\u6e21\u91d1\u5c5e\uff0c\u8fd9\u4e0e\u91d1\u5c5e\u7684\u7ed3\u6784\u3001\u8868\u9762\u5316\u5b66\u952e\u6709\u5173\u3002\u91d1\u5c5e\u9002\u5408\u4e8e\u4f5c\u54ea\u79cd\u7c7b\u578b\u7684\u50ac\u5316\u5242\uff0c\u8981\u770b\u5176\u5bf9\u53cd\u5e94\u7269\u7684\u76f8\u5bb9\u6027\u3002\u53d1\u751f\u50ac\u5316\u53cd\u5e94\u65f6\uff0c\u50ac\u5316\u5242\u4e0e\u53cd\u5e94\u7269\u8981\u76f8\u4e92\u4f5c\u7528\u3002\u9664\u8868\u9762\u5916\uff0c\u4e0d\u6df1\u5165\u5230\u4f53\u5185\uff0c\u6b64\u5373\u76f8\u5bb9\u6027\u3002\u5982\u8fc7\u6e21\u91d1\u5c5e\u662f\u5f88\u597d\u7684\u52a0\u6c22\u3001\u8131\u6c22\u50ac\u5316\u5242\uff0c\u56e0\u4e3aH2\u5f88\u5bb9\u6613\u5728\u5176\u8868\u9762\u5438\u9644\uff0c\u53cd\u5e94\u4e0d\u8fdb\u884c\u5230\u8868\u5c42\u4ee5\u4e0b\u3002\u4f46\u53ea\u6709\u201c\u8d35\u91d1\u5c5e\u201d\uff08Pd\u3001Pt\uff0c\u4e5f\u6709Ag\uff09\u53ef\u4f5c\u6c27\u5316\u53cd\u5e94\u50ac\u5316\u5242\uff0c\u56e0\u4e3a\u5b83\u4eec\u5728\u76f8\u5e94\u6e29\u5ea6\u4e0b\u80fd\u6297\u62d2\u6c27\u5316\u3002\u6545\u5bf9\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6df1\u5165\u8ba4\u8bc6\uff0c\u8981\u4e86\u89e3\u5176\u5438\u9644\u6027\u80fd\u548c\u5316\u5b66\u952e\u7279\u6027\u3002<\/p>\n

2\uff0e\u91d1\u5c5e\u548c\u91d1\u5c5e\u8868\u9762\u7684\u5316\u5b66\u952e<\/p>\n

\u7814\u7a76\u91d1\u5c5e\u5316\u5b66\u952e\u7684\u7406\u8bba\u65b9\u6cd5\u6709\u4e09\uff1a\u80fd\u5e26\u7406\u8bba\u3001\u4ef7\u952e\u7406\u8bba\u548c\u914d\u4f4d\u573a\u7406\u8bba\uff0c\u5404\u81ea\u4ece\u4e0d\u540c\u7684\u89d2\u5ea6\u6765\u8bf4\u660e\u91d1\u5c5e\u5316\u5b66\u952e\u7684\u7279\u5f81\uff0c\u6bcf\u4e00\u79cd\u7406\u8bba\u90fd\u63d0\u4f9b\u4e86\u4e00\u4e9b\u6709\u7528\u7684\u6982\u5ff5\u3002\u4e09\u79cd\u7406\u8bba\uff0c\u90fd\u53ef\u7528\u7279\u5b9a\u7684\u53c2\u91cf\u4e0e\u91d1\u5c5e\u7684\u5316\u5b66\u5438\u9644\u548c\u50ac\u5316\u6027\u80fd\u76f8\u5173\u8054\uff0c\u5b83\u4eec\u662f\u76f8\u8f85\u76f8\u6210\u7684\u3002<\/p>\n

\uff081\uff09\u91d1\u5c5e\u7535\u5b50\u7ed3\u6784\u7684\u80fd\u5e26\u6a21\u578b\u548c\u201cd\u5e26\u7a7a\u7a74\u201d\u6982\u5ff5<\/p>\n

\u91d1\u5c5e\u6676\u683c\u4e2d\u6bcf\u4e00\u4e2a\u7535\u5b50\u5360\u7528\u4e00\u4e2a\u201c\u91d1\u5c5e\u8f68\u9053\u201d\u3002\u6bcf\u4e2a\u8f68\u9053\u5728\u91d1\u5c5e\u6676\u4f53\u573a\u5185\u6709\u81ea\u5df1\u7684\u80fd\u7ea7\u3002\u7531\u4e8e\u6709N\u4e2a\u8f68\u9053\uff0c\u4e14N\u5f88\u5927\uff0c\u56e0\u6b64\u8fd9\u4e9b\u80fd\u7ea7\u662f\u8fde\u7eed\u7684\u3002\u7531\u4e8e\u8f68\u9053\u76f8\u4e92\u4f5c\u7528\uff0c\u80fd\u7ea7\u4e00\u5206\u4e3a\u4e8c\uff0c\u6545N\u4e2a\u91d1\u5c5e\u8f68\u9053\u4f1a\u5f62\u62102N\u4e2a\u80fd\u7ea7\u3002\u7535\u5b50\u5360\u7528\u80fd\u7ea7\u65f6\u9075\u4ece\u80fd\u91cf\u4f4e\u539f\u5219\u548cPauli\u539f\u5219\uff08\u5373\u7535\u5b50\u914d\u5bf9\u5360\u7528\uff09\u3002\u6545\u5728\u7edd\u5bf9\u96f6\u5ea6\u4e0b\uff0c\u7535\u5b50\u6210\u5bf9\u4ece\u4f4e\u80fd\u7ea7\u5f00\u59cb\u4e00\u76f4\u5411\u4e0a\u586b\u5145\uff0c\u53ea\u6709\u4e00\u534a\u7684\u80fd\u7ea7\u6709\u7535\u5b50\uff0c\u79f0\u4e3a\u6ee1\u5e26\uff0c\u80fd\u7ea7\u9ad8\u7684\u4e00\u534a\u80fd\u7ea7\u6ca1\u6709\u7535\u5b50\uff0c\u53eb\u7a7a\u5e26\u3002\u7a7a\u5e26\u548c\u6ee1\u5e26\u7684\u5206\u754c\u5904\uff0c\u5373\u7535\u5b50\u5360\u7528\u7684\u9ad8\u80fd\u7ea7\u79f0\u4e3a\u8d39\u7c73\uff08Fermi\uff09\u80fd\u7ea7\u3002<\/p>\n

s\u8f68\u9053\u5f62\u6210s\u5e26\uff0cd\u8f68\u9053\u7ec4\u6210d\u5e26\uff0cs\u5e26\u548cd\u5e26\u4e4b\u95f4\u6709\u4ea4\u8fed\u3002\u8fd9\u79cd\u60c5\u51b5\u5bf9\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u7279\u522b\u5982\u6b64\uff0c\u4e5f\u5341\u5206\u91cd\u8981\u3002s\u80fd\u7ea7\u4e3a\u5355\u91cd\u6001\uff0c\u53ea\u80fd\u5bb9\u7eb32\u4e2a\u7535\u5b50\uff1bd\u80fd\u7ea7\u4e3a5\u91cd\u7b80\u5e76\u6001\uff0c\u53ef\u4ee5\u5bb9\u7eb310\u4e2a\u7535\u5b50\u3002\u5982\u94dc\u7684\u7535\u5b50\u7ec4\u6001\u4e3a[Cu](3d10)(4s1)\uff0c\u6545\u91d1\u5c5e\u94dc\u4e2dd\u5e26\u7535\u5b50\u662f\u5145\u6ee1\u7684\uff0c\u4e3a\u6ee1\u5e26\uff1b\u800cs\u5e26\u53ea\u5360\u7528\u4e00\u534a\u3002\u954d\u539f\u5b50\u7684\u7535\u5b50\u7ec4\u6001\u4e3a[Ni] (3d5)(4s2)\uff0c\u6545\u91d1\u5c5e\u954d\u7684d\u5e26\u4e2d\u67d0\u4e9b\u80fd\u7ea7\u672a\u88ab\u5145\u6ee1\uff0c\u79f0\u4e3a\u201cd\u5e26\u7a7a\u7a74\u201d\u3002\u201cd\u5e26\u7a7a\u7a74\u201d\u7684\u6982\u5ff5\u5bf9\u4e8e\u7406\u89e3\u8fc7\u6e21\u91d1\u5c5e\u7684\u5316\u5b66\u5438\u9644\u548c\u50ac\u5316\u4f5c\u7528\u662f\u81f3\u5173\u91cd\u8981\u7684\uff0c\u56e0\u4e3a\u4e00\u4e2a\u80fd\u5e26\u7535\u5b50\u5168\u5145\u6ee1\u65f6\uff0c\u5b83\u5c31\u96be\u4e8e\u6210\u952e\u4e86\u3002<\/p>\n

\uff082\uff09\u4ef7\u952e\u6a21\u578b\u548cd\u7279\u6027\u767e\u5206\u6570\uff08d%\uff09\u7684\u6982\u5ff5<\/p>\n

\u4ef7\u952e\u7406\u8bba\u8ba4\u4e3a\uff0c\u8fc7\u6e21\u91d1\u5c5e\u539f\u5b50\u4ee5\u6742\u5316\u8f68\u9053\u76f8\u7ed3\u5408\u3002\u6742\u5316\u8f68\u9053\u901a\u5e38\u4e3as\u3001p\u3001d\u7b49\u539f\u5b50\u8f68\u9053\u7684\u7ebf\u6027\u7ec4\u5408\uff0c\u79f0\u4e4b\u4e3aspd\u6216dsp\u6742\u5316\u3002\u6742\u5316\u8f68\u9053\u4e2dd\u539f\u5b50\u8f68\u9053\u6240\u5360\u7684\u767e\u5206\u6570\u79f0\u4e3ad\u7279\u6027\u767e\u5206\u6570\uff0c\u7528\u7b26\u53f7d%\u8868\u793a\u3002\u5b83\u662f\u4ef7\u952e\u7406\u8bba\u7528\u4ee5\u5173\u8054\u91d1\u5c5e\u50ac\u5316\u6d3b\u6027\u548c\u5176\u4ed6\u7269\u6027\u7684\u4e00\u4e2a\u7279\u6027\u53c2\u6570\u3002<\/p>\n

\u91d1\u5c5ed%\u8d8a\u5927\uff0c\u76f8\u5e94\u7684d\u80fd\u5e26\u4e2d\u7684\u7535\u5b50\u586b\u5145\u8d8a\u591a\uff0cd\u7a7a\u7a74\u5c31\u8d8a\u5c11\u3002d%\u548cd\u7a7a\u7a74\u662f\u4ece\u4e0d\u540c\u89d2\u5ea6\u53cd\u6620\u91d1\u5c5e\u7535\u5b50\u7ed3\u6784\u7684\u53c2\u91cf\uff0c\u4e14\u662f\u76f8\u53cd\u7684\u7535\u5b50\u7ed3\u6784\u8868\u5f81\u3002\u5b83\u4eec\u5206\u522b\u4e0e\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5316\u5b66\u5438\u9644\u548c\u50ac\u5316\u6d3b\u6027\u6709\u67d0\u79cd\u5173\u8054\u3002\u5c31\u5e7f\u4e3a\u5e94\u7528\u7684\u91d1\u5c5e\u52a0\u6c22\u50ac\u5316\u5242\u6765\u8bf4\uff0cd%\u572840~50%\u4e3a\u5b9c\u3002<\/p>\n

(3) \u914d\u4f4d\u573a\u6a21\u578b<\/p>\n

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3\u91d1\u5c5e\u7684\u4f53\u76f8\u7ed3\u6784\u3001\u8868\u9762\u7ed3\u6784\u3001\u6676\u683c\u7f3a\u9677\u4e0e\u4f4d\u9519 \uff081\uff09\u91d1\u5c5e\u7684\u4f53\u76f8\u7ed3\u6784<\/p>\n

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