{"id":4123,"date":"2024-07-24T08:53:36","date_gmt":"2024-07-24T00:53:36","guid":{"rendered":"\/\/www.30-onna.com\/?p=4123"},"modified":"2024-07-24T08:53:36","modified_gmt":"2024-07-24T00:53:36","slug":"%e7%82%94%e7%83%83%e5%a4%8d%e5%88%86%e8%a7%a3%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.30-onna.com\/archives\/4123","title":{"rendered":"\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94"},"content":{"rendered":"

\u7094\u70c3\u590d\u5206\u89e3<\/strong><\/a>\u53cd\u5e94<\/p>\n

\u7094\u70c3\u5173\u73af\u590d\u5206\u89e3<\/p>\n

\u91d1\u5c5e\u50ac\u5316\u4e0b\uff0c\u78b3\u78b3\u4e09\u952e\u7684\u65ad\u88c2\u91cd\u7ec4\u5f62\u6210\u65b0\u7684\u7094\u70c3\u7684\u53cd\u5e94\u88ab\u79f0\u4e3a\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u3002<\/p>\n

Jacobsen\u2013Katsuki\u73af\u6c27\u5316\u53cd\u5e94<\/p>\n

\u5229\u7528Mn(III)salen\u50ac\u5316\u5242\u50ac\u5316\u4e0b\u6c27\u5316(Z)\u70ef\u70c3\u4e0d\u5bf9\u79f0\u5408\u6210\u73af\u6c27\u5316\u7269\u7684\u53cd\u5e94\u3002<\/p>\n

\u5e38\u7528\u50ac\u5316\u5242—-(R,R)-Jacobsen \u50ac\u5316\u5242<\/p>\n

Jacobsen\u6c34\u89e3\u52a8\u529b\u5b66\u62c6\u5206<\/p>\n

\"\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u63d2\u56fe\"<\/p>\n

\u82ef\u915a\uff0c\u70ef\u9187\uff0c\u5511\u7c7b\uff0c\u7094\u53ca\u5176\u4ed6C-, O-\u548cN-\u8d1f\u79bb\u5b50\u548c\u4e09\u4ef7\u6216\u4e94\u4ef7\u6709\u673a\u94cb\u8bd5\u5242\u4f5c\u7528\u8fdb\u884c\u82b3\u57fa\u5316\u7684\u53cd\u5e94\u3002\u6b64\u7c7b\u53cd\u5e94\u5728\u4e2d\u6027\uff0c\u9178\u6027\u6216\u78b1\u6027\u6761\u4ef6\u4e0b\u90fd\u53ef\u4ee5\u8fdb\u884c\u3002N\u82b3\u57fa\u5316\u53ef\u4ee5\u5728\u918b\u9178\u94dc\u5b58\u5728\u4e0b\uff0c\u4e0eAr3Bi\uff08\u53ef\u4ee5\u7531ArLi\u6216ArMgX\u548c\u4e09\u6c2f\u5316\u94cb\u53cd\u5e94\u5236\u5f97\uff09\u53cd\u5e94\u5b9e\u73b0\uff0c\u9187\u7c7b\u7684O\u82b3\u57fa\u5316\u53ef\u4ee5\u5728\u918b\u9178\u94dc\u5b58\u5728\u4e0b\u548cAr4BiF\u53cd\u5e94\u5f97\u5230\u3002<\/p>\n

\u4f4e\u4ef7\u949b[\u5982TiCl3\/LiAlH4\u751f\u6210\u7684Ti(0)]\u50ac\u5316\u7fb0\u57fa\u5236\u5907\u70ef\u70c3\u7684\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u662f\u5355\u7535\u5b50\u8f6c\u79fb\u5386\u7a0b\u3002<\/p>\n

\u5728Ti\u50ac\u5316\u4e0b\u683c\u6c0f\u8bd5\u5242\u548c\u70ef\u70c3\u6216\u7094\u70c3\u8fdb\u884c\u4ea4\u6362\u5f97\u5230\u65b0\u7684\u683c\u6c0f\u8bd5\u5242\uff0c\u518d\u548c\u4e00\u4e9b\u4eb2\u7535\u8bd5\u5242\uff08\u6c27\u6c14\uff0c\u4e8c\u6c27\u5316\u78b3\uff0c\u919b\uff0c\u8148\u7b49\u7b49\uff09\u8fdb\u884c\u683c\u6c0f\u53cd\u5e94\u3002\u7aef\u57fa\u7845\u4fdd\u62a4\u7684\u7094\u4e19\u9187\u548c\u8148\u53d1\u751f\u6b64\u53cd\u5e94\u53ef\u4ee5\u5236\u5907\u5404\u79cd\u53d6\u4ee3\u544b\u5583\u3002<\/p>\n

\"\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u63d2\u56fe1\"<\/p>\n

Cr-Ni\u53cc\u91d1\u5c5e\u50ac\u5316\u4e0b\u70ef\u57fa\uff0c\u7094\u4e19\u57fa\uff0c\u7094\u57fa\u5364\u4ee3\u7269\u5148\u6c27\u5316\u52a0\u6210\u5f97\u5230\u6709\u673a\u4e09\u4ef7\u94ec\u8bd5\u5242\uff0c\u7136\u540e\u5bf9\u919b\u8fdb\u884c\u4eb2\u6838\u52a0\u6210\u5f97\u5230\u9187\u7684\u53cd\u5e94\u3002<\/p>\n

\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u662f\u6307\u5229\u7528\u91d1\u5c5e\u50ac\u5316\u5242\u5b9e\u73b0\u7fa7\u9178\u7c7b\u5316\u5408\u7269\u8131\u7fa7\u5e76\u5728\u539f\u6765\u7684\u7fa7\u9178\u4f4d\u70b9\u751f\u6210\u65b0\u7684\u78b3-\u78b3\u952e\u7684\u5316\u5b66\u53cd\u5e94\u3002\u5e7f\u4e49\u4e0a\u6765\u8bf4\uff0c\u4e5f\u53ef\u4ee5\u5c06\u91d1\u5c5e\u50ac\u5316\u7fa7\u9178\u8131\u7fa7\u5e76\u751f\u6210\u78b3\u6742\u539f\u5b50\u5316\u5b66\u952e\uff08\u78b3-\u6c27\uff0c\u78b3-\u786b\uff0c\u78b3-\u6c2e\u952e\u7b49\uff09\u7684\u53cd\u5e94\u5f52\u7c7b\u4e3a\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u3002\u4f20\u7edf\u6709\u673a\u5316\u5b66\u4e2d\u7684\u8131\u7fa7\u53cd\u5e94\u4e3b\u8981\u5229\u7528\u4e86\u6c27\u5316\u7fa7\u9178\u751f\u6210\u81ea\u7531\u57fa\u7684\u8fc7\u7a0b\u3002\u82b3\u57fa\u548c\u70ef\u57fa\uff08Csp2-COOH\uff09 \u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u4e3b\u8981\u5229\u7528\u91d1\u5c5e\u50ac\u5316\u5b9e\u73b0\u6c27\u5316\u8fd8\u539f\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684\u8131\u7fa7\uff0c\u5e76\u4e14\u751f\u6210\u91d1\u5c5e\u6709\u673a\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u5b9e\u73b0\u4e0e\u4eb2\u7535\u8bd5\u5242\u6216\u8005\u5728\u6c27\u5316\u6027\u6761\u4ef6\u4e0b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u5076\u8054\u6210\u952e\u3002\u867d\u7136\u4e00\u4e9b\u6d3b\u5316\u7684\u70f7\u57fa\u7fa7\u9178\u53ef\u4ee5\u5728\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u4e0b\u901a\u8fc7\u751f\u6210\u91d1\u5c5e\u6709\u673a\u4e2d\u95f4\u4f53\u7684\u5386\u7a0b\u8fdb\u884c\u975e\u81ea\u7531\u57fa\u8131\u7fa7\u5076\u8054\u3002\u4f46\u662f\uff0c\u9488\u5bf9\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u70f7\u57fa\u7fa7\u9178\uff08Csp3-COOH\uff09\u7684\u8131\u7fa7\u56f0\u96be\u95ee\u9898\uff0c\u4e00\u4e9b\u70f7\u57fa\u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u4ecd\u7136\u9700\u8981\u901a\u8fc7\u81ea\u7531\u57fa\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u3002\u503c\u5f97\u6307\u51fa\u7684\u662f\uff0c\u6700\u8fd1\uff0cMacMillan\u7b49\u4eba\u6210\u529f\u5c06\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u4e0e\u954d\u50ac\u5316\u5242\u7ed3\u5408\uff0c\u901a\u8fc7\u7ed3\u5408\u5149\u50ac\u5316\u4e0e\u91d1\u5c5e\u6709\u673a\u50ac\u5316\u7684\u6df7\u5408\u624b\u6bb5\uff0c\u5b9e\u73b0\u4e86\u6c28\u57fa\u9178\u548c\u975e\u6d3b\u5316\u70f7\u57fa\u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u3002<\/p>\n

\"\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u63d2\u56fe2\"<\/p>\n

Kagan-Molander\u5076\u8054\u53cd\u5e94<\/p>\n

\u4e0a\u4e16\u7eaa70\u5e74\u4ee3\u672b\uff0cH. Kagan\u7cfb\u7edf\u5730\u7684\u7814\u7a76\u4e86\u4e8c\u4ef7\u9567\u7cfb\u91d1\u5c5e\u7898\u5316\u7269\u7684\u8fd8\u539f\u7279\u6027\uff0c\u5e76\u5728\u8fd9\u4e00\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u53d1\u73b0\u5728\u4e24\u500d\u5f53\u91cf\u7684\u4e8c\u7898\u5316\u9490\u5b58\u5728\u4e0b\u6eb4\u4ee3\u70f7\uff0c\u7898\u4ee3\u70f7\u6216TsO\u70f7\u4e0e\u919b\u916e\u53cd\u5e94\u53ef\u4ee5\u751f\u6210\u76f8\u5e94\u7684\u9187\u3002\u6700\u521d\u7684\u53cd\u5e94\u6761\u4ef6\u662f\u4ee5\u56db\u6c22\u544b\u5583\u4e3a\u6eb6\u5242\u5ba4\u6e29\u4e0b\u53cd\u5e9424\u5c0f\u65f6\u6216\u56de\u6d41\u51e0\u5c0f\u65f6\u3002Kagan\u4e5f\u53d1\u73b0\u5728\u53cd\u5e94\u4e2d\u52a0\u5165\u50ac\u5316\u91cf\u7684\u6c2f\u5316\u94c1\u53ef\u4ee5\u660e\u663e\u5730\u51cf\u5c11\u53cd\u5e94\u65f6\u95f4\uff0c\u800c\u8fd9\u4e00\u65b9\u6cd5\u5728\u540e\u6765\u88abG.A. Molander\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\u53d1\u5c55\u3002\u57281984\u5e74G.A.Molander\u7b2c\u4e00\u6b21\u62a5\u9053\u4e86\u5728\u5206\u5b50\u5185\u53d1\u751f\u7684\u6b64\u53cd\u5e94\uff0c\u03c9-\u7898\u4ee3\u916f\u5728\u4e8c\u7898\u5316\u9490\u548c\u50ac\u5316\u91cf\u7684\u4e09\u4ef7\u94c1\u76d0\u7684\u5b58\u5728\u4e0b\u53d1\u751f\u5206\u5b50\u5185\u7684\u9170\u57fa\u53d6\u4ee3\u53cd\u5e94\uff0c\u5e76\u8fdb\u4e00\u6b65\u53d1\u751f\u6b64\u53cd\u5e94\u751f\u6210\u590d\u5408\u591a\u73af\u8102\u70c3\u3002\u73b0\u5728\u6b64\u7c7b\u53cd\u5e94\u88ab\u7edf\u79f0\u4e3aKagan-Molander\u4e8c\u7898\u5316\u9490\u4ecb\u5bfc\u5076\u8054\u3002<\/p>\n

\"\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u63d2\u56fe3\"<\/p>\n

Sharpless\u4e0d\u5bf9\u79f0\u53cc\u7f9f\u57fa\u5316\u53cd\u5e94<\/p>\n

\u56db\u6c27\u5316\u9507\u6c27\u5316\uff0cUpjohn\u53cc\u7f9f\u5316\u53cd\u5e94\u673a\u7406\u56fe<\/p>\n

\u5728\u50ac\u5316\u91cf\u7684\u56db\u6c27\u5316\u9507\u548c\u5171\u6c27\u5316\u5242\u7684\u5b58\u5728\u4e0b\uff0c\u70ef\u70c3\u88ab\u6c27\u5316\u6210\u90bb\u4e8c\u9187\u3002\u901a\u8fc7\u5176\u4ed6\u7684\u8bd5\u5242\u8f83\u96be\u5b9e\u73b0\u7684\u70ef\u70c3\u8f6c\u5316\u6210\u90bb\u4e8c\u9187\u901a\u8fc7\u6b64\u65b9\u6cd5\u80fd\u5f88\u6e29\u548c\u5e73\u7a33\u7684\u8fdb\u884c\u3002\u5c3d\u7ba1\u9507\u4ef7\u683c\u76f8\u5bf9\u6602\u8d35\uff0c\u4e5f\u88ab\u9891\u7e41\u4f7f\u7528\u3002<\/p>\n

\u5e38\u7528\u6c27\u5316\u5242—-\u56db\u6c27\u5316\u9507-\u94c1\u6c30\u5316\u94be<\/p>\n

\u5e38\u7528\u6c27\u5316\u5242—-OsO4\/NMO<\/p>\n

Kochi-F\u00fcrstner\u5076\u8054\u53cd\u5e94(Kochi-F\u00fcrstner Cross Coupling)<\/p>\n

\u5364\u5316\u82b3\u70c3\u30fb\u82b3\u57fa\u4e09\u6c1f\u7532\u78fa\u9178\u30fb\u82b3\u57fa\u78fa\u9178\u76d0\u4e0eGrignard\u8bd5\u5242\u5728\u94c1\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0b\u8fdb\u884c\u7684\u5076\u8054\u53cd\u5e94\u3002\u6c2f\u5316\u82b3\u70c3\u662f\u8be5\u53cd\u5e94\u6700\u597d\u7684\u5e95\u7269\u3002\u800c\u6eb4\u5316\u82b3\u70c3\u4e0e\u7898\u5316\u82b3\u70c3\u5728\u8be5\u6761\u4ef6\u4e0b\u4f18\u5148\u53d1\u751f\u8131\u5364\u7d20\u5316\u53cd\u5e94\u3002<\/p>\n

Luche\u8fd8\u539f<\/p>\n

1978\u5e74\uff0cJ.L. Luche\u62a5\u9053\u4e86\u4f7f\u7528\u9567\u7cfb\u91d1\u5c5e\u6c2f\u5316\u7269\u548c\u787c\u6c22\u5316\u94a0\u7684\u6df7\u5408\u7269\u9009\u62e9\u6027\u5730\u5c06\u03b1,\u03b2-\u4e0d\u9971\u548c\u916e\u8fd8\u539f\u4e3a\u76f8\u5e94\u7684\u70ef\u4e19\u9187\u3002\u5e76\u4e14\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u6b64\u53cd\u5e94\u7684\u5e94\u7528\u8303\u56f4\u548c\u4e00\u4e9b\u9650\u5236\uff0c\u5e76\u53d1\u73b0\u4f7f\u7528CeCl3.7H2O\/NaBH4\u5728\u4e59\u9187\u6216\u7532\u9187\u4e2d\u53cd\u5e94\uff0c\u03b1,\u03b2-\u4e0d\u9971\u548c\u916e\u53d1\u751f1,2-\u8fd8\u539f\u7684\u6548\u679c\u6700\u597d\u3002\u4f7f\u7528\u6c2f\u5316\u94c8\/\u787c\u6c22\u5316\u94a0\u7684\u6df7\u5408\u7269\u5c06\u03b1,\u03b2-\u4e0d\u9971\u548c\u916e\u8fd8\u539f\u4e3a\u76f8\u5e94\u7684\u70ef\u4e19\u9187\u7684\u53cd\u5e94\u88ab\u79f0\u4e3aLuche\u8fd8\u539f\u3002<\/p>\n

\u5e38\u89c1\u7684\u94d1\u50ac\u5316\u53cd\u5e94<\/p>\n","protected":false},"excerpt":{"rendered":"

\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94 \u7094\u70c3\u5173\u73af\u590d\u5206\u89e3 \u91d1\u5c5e\u50ac\u5316\u4e0b\uff0c\u78b3\u78b3\u4e09\u952e\u7684\u65ad\u88c2\u91cd\u7ec4\u5f62\u6210\u65b0\u7684\u7094\u70c3\u7684\u53cd\u5e94\u88ab\u79f0\u4e3a\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u3002 Jacobsen\u2013Katsuki\u73af\u6c27\u5316\u53cd\u5e94 \u5229\u7528Mn(III)salen\u50ac\u5316\u5242\u50ac\u5316\u4e0b\u6c27\u5316(Z)\u70ef… <\/p>\n","protected":false},"author":2,"featured_media":4124,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[45],"tags":[],"_links":{"self":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4123"}],"collection":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/comments?post=4123"}],"version-history":[{"count":1,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4123\/revisions"}],"predecessor-version":[{"id":4128,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4123\/revisions\/4128"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/media\/4124"}],"wp:attachment":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/media?parent=4123"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/categories?post=4123"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/tags?post=4123"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}