{"id":4129,"date":"2024-07-24T09:10:25","date_gmt":"2024-07-24T01:10:25","guid":{"rendered":"\/\/www.30-onna.com\/?p=4129"},"modified":"2024-07-24T09:10:25","modified_gmt":"2024-07-24T01:10:25","slug":"%e9%93%9c%e5%82%ac%e5%8c%96%e7%b1%bb","status":"publish","type":"post","link":"\/\/www.30-onna.com\/archives\/4129","title":{"rendered":"\u94dc\u50ac\u5316\u7c7b"},"content":{"rendered":"<p><a href=\"\/\/www.30-onna.com\/\" target=\"_self\" rel=\"noopener\"><strong>\u94dc\u50ac\u5316\u7c7b<\/strong><\/a><\/p>\n<p>Ullmann\u5076\u8054\u53cd\u5e94<\/p>\n<p>\u7898\u4ee3\u82b3\u70c3\u5728Cu \uff0c Ni \u6216Pd \u50ac\u5316\u4e0b\u8fdb\u884c\u81ea\u8eab\u5076\u8054\u5f97\u5230\u4e8c\u82b3\u57fa\u5316\u5408\u7269\u7684\u53cd\u5e94\u3002<\/p>\n<p>Goldberg\u5076\u8054\u53cd\u5e94<\/p>\n<p>\u94dc\u6216\u94dc\u76d0\u50ac\u5316\u4e0b\u8fdb\u884c\u82b3\u9170\u80fa\u5316\u7684\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u6700\u65e9\u7531\u5fb7\u56fd\u5973\u5316\u5b66\u5bb6\u3001Fritz Ullmann \u7684\u59bb\u5b50 Irma Goldberg \u53d1\u73b0\u3002\u4f46\u6b64\u53cd\u5e94\u6709\u4e00\u4e9b\u7f3a\u70b9\uff1a\uff081\uff09\u53cd\u5e94\u6e29\u5ea6\u4e00\u822c\u662f140\u2103\uff0c\u751a\u81f3\u66f4\u9ad8\uff1b\uff082\uff09\u90e8\u5206\u7684\u53cd\u5e94\u9700\u8981\u4e00\u4e2a\u6469\u5c14\u6216\u66f4\u591a\u7684\u94dc\u53c2\u4e0e\u53cd\u5e94\uff1b\uff083\uff09\u4e00\u822c\u9700\u8981\u5728\u9ad8\u6781\u6027\u800c\u4e14\u6bd2\u6027\u8f83\u5927\u7684\u6eb6\u5242\u4e2d\u8fdb\u884c\u3002\u8fd1\u5e74\u6765\uff0c\u5229\u7528\u5408\u9002\u7684\u914d\u4f53\uff0c\u628a\u94dc\u7684\u4f7f\u7528\u91cf\u7f29\u51cf\u5230\u4e86\u50ac\u5316\u91cf\u3002\u8be5\u53cd\u5e94\u4e0d\u9700\u8981\u4f7f\u7528\u6602\u8d35\u7684Pd\u91d1\u5c5e\uff0c\u5728\u7ecf\u6d4e\u6027\u4e0a\u662f\u5341\u5206\u6709\u4f18\u52bf\u7684\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-4130\" src=\"\/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1701515866587-2.jpg\" width=\"800\" height=\"600\" srcset=\"\/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1701515866587-2.jpg 800w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1701515866587-2-350x263.jpg 350w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1701515866587-2-768x576.jpg 768w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1701515866587-2-220x165.jpg 220w\" sizes=\"(max-width: 800px) 100vw, 800px\" title=\"\u94dc\u50ac\u5316\u7c7b\u63d2\u56fe\" alt=\"\u94dc\u50ac\u5316\u7c7b\u63d2\u56fe\" \/><\/p>\n<p>Kinugasa \u03b2-\u5185\u9170\u80fa\u5408\u6210\u53cd\u5e94<\/p>\n<p>\u624b\u6027\u6709\u673a\u94dc\uff08\u624b\u6027\u6076\u5511\u5549\uff09\u50ac\u5316\u5242\u50ac\u5316\u4e0b\uff0c\u7aef\u57fa\u7094\u548c\u785d\u916e\u8fdb\u884c\u5076\u6781\u73af\u52a0\u6210\u5f97\u5230\u5f02\u6076\u5511\u5549\u4e2d\u95f4\u4f53\uff0c\u91cd\u6392\u540e\u5f97\u5230\u7acb\u4f53\u9009\u62e9\u6027\u7684\u03b2-\u5185\u9170\u80fa\u7684\u53cd\u5e94\u3002<\/p>\n<p>Meerwein\u82b3\u57fa\u5316\u53cd\u5e94<\/p>\n<p>Feringa\u2013Alexakis\u4e0d\u5bf9\u79f0\u8fc8\u514b\u5c14\u52a0\u6210\u53cd\u5e94<\/p>\n<p>\u5728\u624b\u6027\u8054\u4e8c\u8418\u7c7b\u914d\u4f53\u548cCu(II)\u50ac\u5316\u4e0b\uff0c\u70f7\u57fa\u950c\u5bf9\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\u6216\u4e0d\u9971\u548c\u916e\u4e9a\u80fa\u8fdb\u884c\u4e0d\u5bf9\u79f0\u8fc8\u514b\u5c14\u52a0\u6210\u7684\u53cd\u5e94\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-4131\" src=\"\/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1683642646593-1.jpg\" width=\"800\" height=\"600\" srcset=\"\/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1683642646593-1.jpg 800w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1683642646593-1-350x263.jpg 350w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1683642646593-1-768x576.jpg 768w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1683642646593-1-220x165.jpg 220w\" sizes=\"(max-width: 800px) 100vw, 800px\" title=\"\u94dc\u50ac\u5316\u7c7b\u63d2\u56fe1\" alt=\"\u94dc\u50ac\u5316\u7c7b\u63d2\u56fe1\" 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srcset=\"\/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1686988440199.jpg 1280w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1686988440199-350x350.jpg 350w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1686988440199-1024x1024.jpg 1024w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1686988440199-200x200.jpg 200w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1686988440199-768x768.jpg 768w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1686988440199-300x300.jpg 300w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1686988440199-1170x1170.jpg 1170w, \/\/www.30-onna.com\/wp-content\/uploads\/2024\/07\/1686988440199-220x220.jpg 220w\" sizes=\"(max-width: 1280px) 100vw, 1280px\" title=\"\u94dc\u50ac\u5316\u7c7b\u63d2\u56fe2\" alt=\"\u94dc\u50ac\u5316\u7c7b\u63d2\u56fe2\" \/><\/p>\n<p>\u954d\u50ac\u5316\u7c7b<\/p>\n<p>Kumada\u5076\u8054\u53cd\u5e94<\/p>\n<p>Kumada\u5076\u8054\u53cd\u5e94\u662f1972\u5e74\u9996\u5148\u53d1\u73b0\u7684Pd \u6216 Ni\u50ac\u5316\u7684\u5076\u8054\u53cd\u5e94\uff0c\u6b64\u53cd\u5e94\u662f\u683c\u6c0f\u8bd5\u5242\u548c\u70f7\u57fa\uff0c\u70ef\u57fa\u6216\u82b3\u57fa\u5364\u4ee3\u7269\u5076\u8054\u7684\u5f88\u7ecf\u6d4e\u7684\u53cd\u5e94\uff0c\u7f3a\u70b9\u662f\u5e76\u4e0d\u662f\u6240\u6709\u7684\u5364\u4ee3\u7269\u90fd\u80fd\u4e0e\u6709\u673a\u9541\u5316\u5408\u7269\u8fdb\u884c\u53cd\u5e94\u3002Kumada\u5076\u8054\u5728\u5de5\u4e1a\u4e0a\u7684\u4e00\u4e2a\u91cd\u8981\u5e94\u7528\u662f\u5408\u6210\u82ef\u4e59\u70ef\u7c7b\u884d\u751f\u7269\uff0c\u662f\u4f4e\u6210\u672c\u5408\u6210\u4e0d\u5bf9\u79f0\u7684\u8054\u82b3\u57fa\u5316\u5408\u7269\u7684\u53cd\u5e94\u3002<\/p>\n<p>\u672c\u53cd\u5e94\u4e0eNegishi Coupling\u4e0d\u540c\uff0c\u53ef\u4ee5\u76f4\u63a5\u548c\u683c\u6c0f\u8bd5\u5242\u53cd\u5e94\uff0c\u800c\u4e0d\u9700\u8981\u5148\u8f6c\u5316\u4e3a\u6709\u673a\u950c\u8bd5\u5242\u3002<\/p>\n<p>Kumada\uff08\u4ea4\u53c9\uff09\u5076\u8054\u53cd\u5e94\uff08\u718a\u7530\u5076\u8054\uff1bKumadacoupling\uff09\uff0c\u53c8\u79f0Kumada-Corriu\uff08\u4ea4\u53c9\uff09\u5076\u8054\u53cd\u5e94\uff0c\u718a\u7530-\u7389\u5c3e-Corriu\u5076\u8054\u53cd\u5e94(Kumada-Tamao-Corriu Cross Coupling)\u3002\u662f\u6307\u70f7\u57fa\u6216\u82b3\u57fa\u683c\u6c0f\u8bd5\u5242\u4e0e\u82b3\u5364\u6216\u4e59\u70ef\u57fa\u5364\uff0c\u82b3\u57fa\u4e09\u6c1f\u7532\u78fa\u9178\u916f\u7b49\u7b49\u5728\u954d\u6216\u94af\u50ac\u5316\u4e0b\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u3002<\/p>\n<p>Negishi\u4ea4\u53c9\u5076\u8054\u53cd\u5e94<\/p>\n<p>\u5728\u954d\u6216\u94af\u50ac\u5316\u4e0b\u6709\u673a\u950c\u8bd5\u5242\u548c\u5404\u79cd\u5364\u4ee3\u7269\u6216\u78fa\u9178\u916f\uff08\u82b3\u57fa\uff0c\u70ef\u57fa\uff0c\u7094\u57fa\u548c\u9170\u57fa\uff09\u8fdb\u884c\u4ea4\u53c9\u5076\u8054\u7684\u53cd\u5e94\u3002<\/p>\n<p>\u53cd\u5e94\u6d3b\u6027\u4e00\u822c\u6bd4\u8f83\u597d\u3001\u5bf9\u70f7\u57fa(sp3) \u950c\u5316\u5408\u7269\u4e5f\u80fd\u4f7f\u7528\uff0c\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u597d\u3002<\/p>\n<p>\u53e6\u5916\u4f7f\u7528\u6709\u673a\u94dd\u6216\u6709\u673a\u9506\u7684\u5076\u8054\u53cd\u5e94\u4e5f\u88ab\u79f0\u4e3a\u6839\u5cb8\u5076\u8054\u53cd\u5e94\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u94dc\u50ac\u5316\u7c7b Ullmann\u5076\u8054\u53cd\u5e94 \u7898\u4ee3\u82b3\u70c3\u5728Cu \uff0c Ni \u6216Pd \u50ac\u5316\u4e0b\u8fdb\u884c\u81ea\u8eab\u5076\u8054\u5f97\u5230\u4e8c\u82b3\u57fa\u5316\u5408\u7269\u7684\u53cd\u5e94\u3002 Goldberg\u5076\u8054\u53cd\u5e94 \u94dc\u6216\u94dc\u76d0\u50ac\u5316\u4e0b\u8fdb\u884c\u82b3\u9170\u80fa\u5316\u7684\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u6700\u65e9\u7531\u5fb7\u56fd\u5973\u5316\u5b66\u5bb6\u3001F&#8230; <\/p>\n","protected":false},"author":2,"featured_media":4130,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[45],"tags":[],"_links":{"self":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4129"}],"collection":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/comments?post=4129"}],"version-history":[{"count":1,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4129\/revisions"}],"predecessor-version":[{"id":4133,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4129\/revisions\/4133"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/media\/4130"}],"wp:attachment":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/media?parent=4129"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/categories?post=4129"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/tags?post=4129"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}