\u6709\u673a\u53cd\u5e94\u673a\u7406<\/strong><\/a><\/p>\n\u53cd\u5e94\u673a\u7406<\/p>\n
\u8fc7\u9178\u5148\u4e0e\u7fb0\u57fa\u8fdb\u884c\u4eb2\u6838\u52a0\u6210\uff0c\u7136\u540e\u916e\u7fb0\u57fa\u4e0a\u7684\u4e00\u4e2a\u70c3\u57fa\u5e26\u7740\u4e00\u5bf9\u7535\u5b50\u8fc1\u79fb\u5230-O-O-\u57fa\u56e2\u4e2d\u4e0e\u7fb0\u57fa\u78b3\u539f\u5b50\u76f4\u63a5\u76f8\u8fde\u7684\u6c27\u539f\u5b50\u4e0a\uff0c\u540c\u65f6\u53d1\u751fO-O\u952e\u5f02\u88c2\u3002\u56e0\u6b64\uff0c\u8fd9\u662f\u4e00\u4e2a\u91cd\u6392\u53cd\u5e94<\/p>\n
\u5177\u6709\u5149\u5b66\u6d3b\u6027\u76843—\u82ef\u57fa\u4e01\u916e\u548c\u8fc7\u9178\u53cd\u5e94\uff0c\u91cd\u6392\u4ea7\u7269\u624b\u6027\u78b3\u539f\u5b50\u7684\u67b8\u578b\u4fdd\u6301\u4e0d\u53d8\uff0c\u8bf4\u660e\u53cd\u5e94\u5c5e\u4e8e\u5206\u5b50\u5185\u91cd\u6392\uff1a<\/p>\n
\u4e0d\u5bf9\u79f0\u7684\u916e\u6c27\u5316\u65f6\uff0c\u5728\u91cd\u6392\u6b65\u9aa4\u4e2d\uff0c\u4e24\u4e2a\u57fa\u56e2\u5747\u53ef\u8fc1\u79fb\uff0c\u4f46\u662f\u8fd8\u662f\u6709\u4e00\u5b9a\u7684\u9009\u62e9\u6027\uff0c\u6309\u8fc1\u79fb\u80fd\u529b\u5176\u987a\u5e8f\u4e3a\uff1a<\/p>\n
\u919b\u6c27\u5316\u7684\u673a\u7406\u4e0e\u6b64\u76f8\u4f3c\uff0c\u4f46\u8fc1\u79fb\u7684\u662f\u6c22\u8d1f\u79bb\u5b50\uff0c\u5f97\u5230\u7fa7\u9178\u3002<\/p>\n
<\/p>\n
\u53cd\u5e94\u5b9e\u4f8b<\/p>\n
\u916e\u7c7b\u5316\u5408\u7269\u7528\u8fc7\u9178\u5982\u8fc7\u6c27\u3001\u8fc7\u6c27\u82ef\u7532\u9178\u3001\u95f4\u6c2f\u8fc7\u6c27\u82ef\u7532\u9178\u6216\u4e09\u6c1f\u8fc7\u6c27\u7b49\u6c27\u5316\uff0c\u53ef\u5728\u7fb0\u57fa\u65c1\u8fb9\u63d2\u5165\u4e00\u4e2a\u6c27\u539f\u5b50\u751f\u6210\u76f8\u5e94\u7684\u916f\uff0c\u5176\u4e2d\u4e09\u6c1f\u8fc7\u6c27\u662f\u975e\u5e38\u597d\u7684\u6c27\u5316\u5242\u3002\u8fd9\u7c7b\u6c27\u5316\u5242\u7684\u7279\u70b9\u662f\u53cd\u5e94\u901f\u7387\u5feb\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e00\u822c\u572810~40\u2103\u4e4b\u95f4\uff0c\u4ea7\u7387\u9ad8\u3002<\/p>\n
Beckmann \u91cd\u6392\u53cd\u5e94<\/p>\n
\u809f\u5728\u9178\u3001\u591a\u805a\u78f7\u9178\u4ee5\u53ca\u80fd\u4ea7\u751f\u5f3a\u9178\u7684\u4e94\u6c2f\u5316\u78f7\u3001\u4e09\u6c2f\u5316\u78f7\u3001\u82ef\u78fa\u9170\u6c2f\u3001\u4e9a\u786b\u9170\u6c2f\u7b49\u4f5c\u7528\u4e0b\u53d1\u751f\u91cd\u6392\uff0c\u751f\u6210\u76f8\u5e94\u7684\u53d6\u4ee3\u9170\u80fa\uff0c\u5982\u73af\u5df1\u916e\u809f\u5728\u4f5c\u7528\u4e0b\u91cd\u6392\u751f\u6210\u5df1\u5185\u9170\u80fa\uff1a<\/p>\n
\u53cd\u5e94\u673a\u7406<\/p>\n
\u5728\u9178\u4f5c\u7528\u4e0b\uff0c\u809f\u9996\u5148\u53d1\u751f\u8d28\u5b50\u5316\uff0c\u7136\u540e\u8131\u53bb\u4e00\u5206\u5b50\u6c34\uff0c\u540c\u65f6\u4e0e\u7f9f\u57fa\u5904\u4e8e\u53cd\u4f4d\u7684\u57fa\u56e2\u8fc1\u79fb\u5230\u7f3a\u7535\u5b50\u7684\u6c2e\u539f\u5b50\u4e0a\uff0c\u6240\u5f62\u6210\u7684\u78b3\u6b63\u79bb\u5b50\u4e0e\u6c34\u53cd\u5e94\u5f97\u5230\u9170\u80fa\u3002<\/p>\n
\u8fc1\u79fb\u57fa\u56e2\u5982\u679c\u662f\u624b\u6027\u78b3\u539f\u5b50\uff0c\u5219\u5728\u8fc1\u79fb\u524d\u540e\u5176\u6784\u578b\u4e0d\u53d8\uff0c\u4f8b\u5982\uff1a<\/p>\n
<\/p>\n
\u53cd\u5e94\u5b9e\u4f8b<\/p>\n
Cannizzaro \u53cd\u5e94<\/p>\n
\u51e1\u03b1\u4f4d\u78b3\u539f\u5b50\u4e0a\u65e0\u6d3b\u6cfc\u6c22\u7684\u919b\u7c7b\u548c\u6d53NaOH\u6216KOH\u6c34\u6216\u9187\u6eb6\u6db2\u4f5c\u7528\u65f6\uff0c\u4e0d\u53d1\u751f\u9187\u919b\u7f29\u5408\u6216\u6811\u8102\u5316\u4f5c\u7528\u800c\u8d77\u6b67\u5316\u53cd\u5e94\u751f\u6210\u4e0e\u919b\u76f8\u5f53\u7684\u9178(\u6210\u76d0)\u53ca\u9187\u7684\u6df7\u5408\u7269\u3002\u6b64\u53cd\u5e94\u7684\u7279\u5f81\u662f\u919b\u81ea\u8eab\u540c\u65f6\u53d1\u751f\u6c27\u5316\u53ca\u8fd8\u539f\u4f5c\u7528\uff0c\u4e00\u5206\u5b50\u88ab\u6c27\u5316\u6210\u9178\u7684\u76d0\uff0c\u53e6\u4e00\u5206\u5b50\u88ab\u8fd8\u539f\u6210\u9187\uff1a<\/p>\n
<\/p>\n
\u8102\u80aa\u919b\u4e2d\uff0c\u53ea\u6709\u7532\u919b\u548c\u4e0e\u7fb0\u57fa\u76f8\u8fde\u7684\u662f\u4e00\u4e2a\u53d4\u78b3\u539f\u5b50\u7684\u919b\u7c7b\uff0c\u624d\u4f1a\u53d1\u751f\u6b64\u53cd\u5e94\uff0c\u5176\u4ed6\u919b\u7c7b\u4e0e\u5f3a\u78b1\u6db2\uff0c\u4f5c\u7528\u53d1\u751f\u9187\u919b\u7f29\u5408\u6216\u8fdb\u4e00\u6b65\u53d8\u6210\u6811\u8102\u72b6\u7269\u8d28\u3002<\/p>\n
\u5177\u6709\u03b1-\u6d3b\u6cfc\u6c22\u539f\u5b50\u7684\u919b\u548c\u7532\u919b\u9996\u5148\u53d1\u751f\u7f9f\u919b\u7f29\u5408\u53cd\u5e94\uff0c\u5f97\u5230\u65e0\u03b1-\u6d3b\u6cfc\u6c22\u539f\u5b50\u7684\u03b2-\u7f9f\u57fa\u919b\uff0c\u7136\u540e\u518d\u4e0e\u7532\u919b\u8fdb\u884c\u4ea4\u53c9Cannizzaro\u53cd\u5e94\uff0c\u5982\u4e59\u919b\u548c\u7532\u919b\u53cd\u5e94\u5f97\u5230\u5b63\u620a\u56db\u9187\uff1a<\/p>\n
\u53cd\u5e94\u673a\u7406<\/p>\n
\u919b\u9996\u5148\u548c\u6c22\u6c27\u6839\u8d1f\u79bb\u5b50\u8fdb\u884c\u4eb2\u6838\u52a0\u6210\u5f97\u5230\u8d1f\u79bb\u5b50\uff0c\u7136\u540e\u78b3\u4e0a\u7684\u6c22\u5e26\u7740\u4e00\u5bf9\u7535\u5b50\u4ee5\u6c22\u8d1f\u79bb\u5b50\u7684\u5f62\u5f0f\u8f6c\u79fb\u5230\u53e6\u4e00\u5206\u5b50\u7684\u7fb0\u57fa\u4e0d\u80fd\u78b3\u539f\u5b50\u4e0a\u3002<\/p>\n
Claisen\u916f\u7f29\u5408\u53cd\u5e94<\/p>\n
\u542b\u6709\u03b1-\u6c22\u7684\u916f\u5728\u9187\u94a0\u7b49\u78b1\u6027\u7f29\u5408\u5242\u4f5c\u7528\u4e0b\u53d1\u751f\u7f29\u5408\u4f5c\u7528\uff0c\u5931\u53bb\u4e00\u5206\u5b50\u9187\u5f97\u5230\u03b2-\u916e\u9178\u916f\u3002\u59822\u5206\u5b50\u5728\u91d1\u5c5e\u94a0\u548c\u5c11\u91cf\u4e0b\u53d1\u751f\u7f29\u5408\u5f97\u5230\u4e59\u9170\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"
\u5316\u5b66\u4e13\u4e1a\u5fc5\u61c2\u7684\u51e0\u4e2a\u6709\u673a\u53cd\u5e94\u673a\u7406 \u53cd\u5e94\u673a\u7406 \u8fc7\u9178\u5148\u4e0e\u7fb0\u57fa\u8fdb\u884c\u4eb2\u6838\u52a0\u6210\uff0c\u7136\u540e\u916e\u7fb0\u57fa\u4e0a\u7684\u4e00\u4e2a\u70c3\u57fa\u5e26\u7740\u4e00\u5bf9\u7535\u5b50\u8fc1\u79fb\u5230-O-O-\u57fa\u56e2\u4e2d\u4e0e\u7fb0\u57fa\u78b3\u539f\u5b50\u76f4\u63a5\u76f8\u8fde\u7684\u6c27\u539f\u5b50\u4e0a\uff0c\u540c\u65f6\u53d1\u751fO-O\u952e\u5f02\u88c2\u3002\u56e0\u6b64\uff0c\u8fd9\u662f\u4e00\u4e2a\u91cd\u6392\u53cd\u5e94… <\/p>\n","protected":false},"author":2,"featured_media":4777,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[45],"tags":[],"_links":{"self":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4776"}],"collection":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/comments?post=4776"}],"version-history":[{"count":1,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4776\/revisions"}],"predecessor-version":[{"id":4780,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/posts\/4776\/revisions\/4780"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/media\/4777"}],"wp:attachment":[{"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/media?parent=4776"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/categories?post=4776"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.30-onna.com\/wp-json\/wp\/v2\/tags?post=4776"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}