{"id":784,"date":"2022-03-22T20:51:54","date_gmt":"2022-03-22T12:51:54","guid":{"rendered":"\/\/www.30-onna.com\/?p=784"},"modified":"2022-03-22T20:51:54","modified_gmt":"2022-03-22T12:51:54","slug":"%e8%81%9a%e6%b0%a8%e9%85%af%e8%bd%af%e6%b3%a1%e9%85%8d%e6%96%b9%e4%b8%ad%e5%82%ac%e5%8c%96%e5%89%82%e8%ae%a1%e7%ae%97","status":"publish","type":"post","link":"\/\/www.30-onna.com\/archives\/784","title":{"rendered":"\u805a\u6c28\u916f\u8f6f\u6ce1\u914d\u65b9\u4e2d\u50ac\u5316\u5242\u8ba1\u7b97"},"content":{"rendered":"

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\n-d(-NCO)\/dt=K0\u00d7(-NCO)\u00d7(-OH)
\nK1\u662f\u5f02\u6c30\u9178\u916f\u4e0e\u7f9f\u57fa\u5316\u5408\u7269\u751f\u6210\u7edc\u5408\u7269\u7684\u6b63\u5411\u53cd\u5e94\u901f\u7387
\nK2\u662f\u5f02\u6c30\u9178\u916f\u4e0e\u7f9f\u57fa\u5316\u5408\u7269\u751f\u6210\u7edc\u5408\u7269\u7684\u8d1f\u5411\u53cd\u5e94\u901f\u7387
\nK3\u662f\u7edc\u5408\u7269\u4e0e\u7f9f\u57fa\u5316\u5408\u7269\u751f\u6210\u6c28\u57fa\u7532\u9178\u916f\u4e0e\u7f9f\u57fa\u5316\u5408\u7269\u7684\u6b63\u5411\u53cd\u5e94\u901f\u7387\u3002
\nK0=[K1\u00d7K3\u00d7(-OH)]\/[K2+K3\u00d7
\nArrhenius\u65b9\u7a0b
\nK=Ae^[-(Ea\/RT)]
\nA\uff1a\u6307\u6570\u56e0\u5b50\u3002
\ne=2.718
\nEa\uff1aKJ\/mol
\nR=8.31(J\/mol.K)
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\n\u952e\u79bb\u80fd(KJ\/mol)
\nC-N205.1~251.2
\nC-C230.2~293.0
\nC-O293.0~314.0
\nN-H351.6~406.0
\nC-H364.9~393.5
\nO-H422.8~460.5
\nC=C418.6~523.3
\nC=O594.1~694.9
\n\u53cd\u5e94\u5f0f
\nRNCO+rOH\u2192RNHCOOr
\nRNCO+HOH\u2192RNHCOOH+RNCO\u2192RNHCONHR+OCO\u2191
\nRNHCOOr+RNCO\u2192RNCONHRCOOr
\nRNHCONHr+RNCO\u2192RNCONHRCONHr
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\n\u4e00\u6b65\u6cd5\u5236\u805a\u6c28\u916f\u65f6\uff0c\u6c28\u57fa\u9178\u7684\u53cd\u5e94\u6d3b\u5316\u80fd\u7ea660(mol.K)\uff0c\u8132\u53cd\u5e94\u6d3b\u5316\u80fd\u4e3a17(mol.K)
\n\u6ce1\u6cab\u4f53\u7cfb\u6bd4\u6eb6\u6db2\u4f53\u7cfb\u60ac\u6d6e\u4f53\u7cfb\u5bb9\u6613\u5b9e\u65bd\u3002\u5206\u6563\u805a\u5408\u5728\u53cd\u5e94\u5f00\u59cb\u65f6\u5373\u51fa\u73b0Norrish-Tromastof\u6548\u5e94\uff0c\u4f7f\u94fe\u589e\u957f\u53c2\u6570\u968f\u65f6\u95f4\u53d8\u5316\u7387\u51cf\u6162\uff0c\u63d0\u9ad8\u4ea7\u54c1\u5355\u5206\u6563\u6027\u3002
\n\u5206\u6563\u805a\u5408\u662f\u7528\u6c14\u4f53\u5c06\u805a\u5408\u4f53\u7cfb\u5206\u9694\u6210\u65e0\u6570\u6b21\u7ec6\u5c0f\u7684\u6ce1\u6cab\u4f7f\u805a\u5408\u7ec4\u4efd\u8f6c\u5316\u4e3a\u6ce1\u6cab\u7684\u8868\u9762\u6db2\u819c\u548c\u8fde\u63a5\u591a\u4e2a\u6db2\u819c\u7684\u201c\u591a\u9762\u8fb9\u754c\u6db2\u80de\u201d\u5f62\u6210\u7279\u6b8a\u5206\u6563\u76f8\u8fdb\u884c\u805a\u5408\u7684\u65b9\u6cd5\u3002
\n\u6ce1\u6cab\u4f53\u7cfb\u4ee5\u6c14\u4f53\u4e3a\u5206\u6563\u4ecb\u8d28\uff0c\u6c14\u4f53\u53d7\u70ed\u81a8\u80c0\u548c\u9038\u51fa\u9aa4\u7136\u51b7\u5374\u6548\u679c\u53ca\u6c14\u4f53\u9038\u51fa\u65f6\u4ea7\u751f\u8d1f\u538b\u5bf9\u4f53\u7cfb\u6b8b\u5b58\u5355\u6d53\u7f29\u4f7f\u4e4b\u8fdb\u4e00\u6b65\u805a\u5408\uff0c\u5bf9\u6c34\u5206\u5b50\u84b8\u53d1\u53ca\u5c0f\u5206\u5b50\u8131\u51fa\u6709\u52a0\u901f\u548c\u643a\u5e26\u4f5c\u7528\u3002
\n\u6c14\u4f53\u5bf9\u805a\u5408\u4f53\u7cfb\u7684\u5206\u6563\u4f5c\u7528\u4e0d\u7b49\u4e8e\u5bf9\u5355\u4f53\u7684\u771f\u6b63\u7a00\u91ca\u3002
\n\u975e\u4e00\u7ea7\u53cd\u5e94\u534a\u8870\u671f\u901a\u5f0f
\nT=[2^(n-1)-1]\/[a\u00d7k\u00d7(n-1)\u00d7A^(n-1)]
\n\u4e8c\u7ea7\u53cd\u5e94\u901f\u7387\u5e38\u6570
\nA+B\u2192Q+S
\nKt=[1\/(CA0-CB0)]\u00d7ln[(CB0\u00d7CA)\/(CA0\u00d7CB)]
\nCA0\u00d7Kt=[1\/(1-M)]\u00d7ln{[M(1-xA)]\/(M-xA)}\u5176\u4e2dM=CB0\/CA0
\n\u2026\u2026<\/p>\n

\"\u805a\u6c28\u916f\u8f6f\u6ce1\u914d\u65b9\u4e2d\u50ac\u5316\u5242\u8ba1\u7b97\u63d2\u56fe\"
\n\u9644\uff1a
\n\u805a\u6c28\u916f\u8f6f\u6ce1\u5bc6\u5ea6\u7684\u8ba1\u7b97\u4e3e\u4f8b
\n\u901a\u7528\u805a\u919a\u4e09\u5143\u9187Ppg\uff1a50pop:50tdi-80\uff1a42.8hoh\uff1a3.17L-580\uff1a1a33\uff1a0.34sn\uff1a0.17
\n\u8ba1\u7b97\u5f97\uff1a4.342.176.5138.2112%17%5.21.74122\u518d\u8ba1\u7b97\u5f97\uff0c28kg\/\u7acb\u65b9\u7c73
\n\u805a\u6c28\u916f\u8f6f\u6ce1\u50ac\u5316\u5242\u8ba1\u7b97\u4e3e\u4f8b
\n\u901a\u7528\u805a\u919a\u4e09\u5143\u9187ppg\uff1a90pop\uff1a10tdi-80\uff1a:35.5hoh\uff1a2.2L-580:0.84\u9ed1\u8272\u6d46\uff1a6
\n\u8ba1\u7b97\u5f97\uff1aA33\uff1a0.18T-9\uff1a0.25
\nA33\uff1a0.14T-9\uff1a0.24
\nA33\uff1a0.13T-9\uff1a0.35
\nA33\uff1a0.12T-9\uff1a0.30
\n\u5bbd\u5bb9\u5ea6\u4e0e\u62d0\u70b9\u2026\u2026
\n\u5782\u6ce1\u53d1\u6ce1\u6d41\u91cf\u4e0e\u63d0\u5347\u901f\u5ea6\u7684\u8ba1\u7b97:
\n\u914d\u65b9(\u4ec5\u4e3e\u4f8b\u7528)PPG:100\uff0cTDI:80\uff0cHOH:6\uff0cSI:1.5\uff0cA33:***\uff0cSN:***\uff0cMC:14.8
\n\u5782\u6ce1\u5706\u6a21\u76f4\u5f841.25\u3002
\n\u805a\u919a\u6d41\u91cf12\u5343\u514b\/\u5206\u949f\u3002
\n\u6c42\u63d0\u5347\u901f\u5ea6\u662f\u591a\u5c11(\u7c73\/\u5206\u949f)
\n\u6c42\u5f97\u914d\u65b9\u5bc6\u5ea612\u5343\u514b\u6bcf\u7acb\u65b9\u3002\u914d\u65b9\u603b\u91cd173.5\u516c\u65a4\u3002\u914d\u65b9\u4f53\u79ef14.46\u7acb\u65b9\u7c73\u3002\u5706\u6a21\u622a\u9762\u79ef:1.23\u5e73\u65b9\u7c73\u3002
\n\u8bbe\u635f\u5931\u73875%\u3002
\n\u63d0\u5347\u901f\u5ea6:[14.46\u00d712%\u00d7(1-5%)]\/1.23=1.34\u7c73\/\u5206\u949f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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